Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-)

Base Information

• Chemical Name: Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-)
• CAS No.: 808142-80-5
• Molecular Formula: C₅₆H₇₂IrN₄*F₆P
• Molecular Weight: 1138.4

Synonyms:

Chemical Property of Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-)

Chemical Property:

• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: air sensitive

Purity/Quality:

97% ^*data from raw suppliers

[4,4'-Di-t-butyl-2,2'-bipyridine][bis[5-(t-butyl)-2-[4-(t-butyl)-2-pyridinyl-kN]phenyl-kC]iridium(III) hexafluorophosphate, 95% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: 36/37/38
• Safety Statements: 26

MSDS Files:

Useful:

Technology Process of Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-)

There total 1 articles about Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ammonium hexafluorophosphate + tetrakis-(4,5'-di-tert-butyl-2-phenylpyridine(-1H))-μ-(dichloro)-diiridium(III) (808142-69-0) + 4,4'-di-tert-butyl-2,2'-bipyridine (72914-19-3) → Ir[(dtbpy)(dtppy)2]PF6 (808142-80-5)

Guidance literature:

In ethylene glycol; Ir complex reacted with ligand in ethylene glycol under reflux for 15 h,cooled to room temp.; transferred to a separatory funnel with H2O, washed (hexanes), the aq. layer heated to 70°C for 5 min, cooled (ice), pptd. (aq. NH4PF6), filtered, air-dried overnight, recrystd. (hexane/acetone vapor diffusion), dried (vac., 100°C, 24 h);

DOI:10.1021/ja047156+

upstream raw materials:

tetrakis-(4,5'-di-tert-butyl-2-phenylpyridine(-1H))-μ-(dichloro)-diiridium(III)

4,4'-di-tert-butyl-2,2'-bipyridine

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