methyl ethyl((E)-1-hexenyl)borinate

Base Information

• Chemical Name: methyl ethyl((E)-1-hexenyl)borinate
• CAS No.: 86942-73-6
• Molecular Formula: C₉H₁₉BO
• Molecular Weight: 154.06
• Mol file: 86942-73-6.mol

Synonyms:

Chemical Property of methyl ethyl((E)-1-hexenyl)borinate

Chemical Property:

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MSDS Files:

Useful:

Technology Process of methyl ethyl((E)-1-hexenyl)borinate

There total 1 articles about methyl ethyl((E)-1-hexenyl)borinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

ethyldibromoborane dimethyl sulfide complex (86942-75-8) + hex-1-yne (693-02-7) → methyl ethyl((E)-1-hexenyl)borinate (86942-73-6) + triethyl borane (53907-92-9)

Guidance literature:

With methanol; lithium aluminium tetrahydride; In carbon disulfide; diethyl ether; to B complex (in SMe2/Et2O) added LiAlH4 (in Et2O) at 0 °C under N2, stirred for 3 h and for 1 h at 25 °C, this soln. added to alkyne (in Et2O) and stirred 1 h each at 0 and 25 °C, added MeOH at -10 °C, stirred for 0.25 h; evapd. in vac., distd.;

DOI:10.1021/om50004a043

upstream raw materials:

ethyldibromoborane dimethyl sulfide complex

hex-1-yne