[2,6-Bis[(di-1-piperidinylphosphino)amino]phenyl]palladium(II) chloride >=98.0% (AT)

Base Information

• Chemical Name: [2,6-Bis[(di-1-piperidinylphosphino)amino]phenyl]palladium(II) chloride >=98.0% (AT)
• CAS No.: 955035-37-7
• Molecular Formula: C₂₆H₄₅ClN₆P₂Pd
• Molecular Weight: 645.504
• Mol file: 955035-37-7.mol

Synonyms:

Chemical Property of [2,6-Bis[(di-1-piperidinylphosphino)amino]phenyl]palladium(II) chloride >=98.0% (AT)

Chemical Property:

• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C

Purity/Quality:

99% ^*data from raw suppliers

[2,6-Bis[(di-1-piperidinylphosphino)amino]phenyl]palladium(II) chloride ≥98.0% (AT) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 38

MSDS Files:

Useful:

• Uses: Palladium catalyst for CC coupling reactionsPerforms Suzuki reactions at low loadingsHigh activity at ppm levels for Heck reactions and Sonogashira couplings

Technology Process of [2,6-Bis[(di-1-piperidinylphosphino)amino]phenyl]palladium(II) chloride >=98.0% (AT)

There total 1 articles about [2,6-Bis[(di-1-piperidinylphosphino)amino]phenyl]palladium(II) chloride >=98.0% (AT) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dicloro(bis(1,1',1''-(phosphinetriyl)tripiperidine))palladium (955117-31-4,68494-72-4) + m-phenylenediamine (108-45-2,64554-26-3,76583-20-5) → [2,6-bis[(di-1-piperidinylphosphino)amino]phenyl]palladium(II) chloride (955035-37-7)

Guidance literature:

In toluene; equimolar amounts of 1,3-diaminobenzene added under N2 to Pd-compd. in toluene, stirred at 100°C for 45 min; volatiles removed under reduced pressure, extracted with Et2O;

DOI:10.1002/anie.200701804

upstream raw materials:

dicloro(bis(1,1',1''-(phosphinetriyl)tripiperidine))palladium

m-phenylenediamine

Refernces