(+)-10,11-Didehydromyoporone

Base Information

• Chemical Name: (+)-10,11-Didehydromyoporone
• CAS No.: 116512-30-2
• Molecular Formula: C₁₅H₂₀O₃
• Molecular Weight: 248.322
• Mol file: 116512-30-2.mol

Synonyms:

Chemical Property of (+)-10,11-Didehydromyoporone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (+)-10,11-Didehydromyoporone

There total 7 articles about (+)-10,11-Didehydromyoporone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

(4R,8RS)-1-(3'-Furyl)-8-hydroxy-4,8-dimethyl-6-nonen-1-one (139609-49-7) → (+)-10,11-Didehydromyoporone (116512-30-2,38462-36-1) + (R)-6-Furan-3-yl-3-methyl-6-oxo-hexanal (139609-50-0)

Guidance literature:

With manganese(II) sulfate; pyridinium chlorochromate; In dichloromethane; for 12h; Ambient temperature;

Reference yield:

furan-3-carboxaldehyde (498-60-2) → (+)-10,11-Didehydromyoporone (116512-30-2,38462-36-1)

Guidance literature:

Multi-step reaction with 4 steps

1: 1) Mg / 1) THF, 15 min, reflux, 2) 2 h

2: 70 percent / pyridinium chlorochromate, NaOAc / CH₂Cl₂ / 0.5 h / Ambient temperature

3: 92 percent / PhSeSePh, Et₄NBr / acetonitrile; H₂O / 6 h / electrolysis

4: 54 percent / pyridinium chlorochromate, manganese sulfate / CH₂Cl₂ / 12 h / Ambient temperature

With manganese(II) sulfate; diphenyl diselenide; tetraethylammonium bromide; sodium acetate; magnesium; pyridinium chlorochromate; In dichloromethane; water; acetonitrile;

Reference yield:

(S)-citronellyl bromide (10340-84-8,4895-14-1,58800-75-2,143615-81-0) → (+)-10,11-Didehydromyoporone (116512-30-2,38462-36-1)

Guidance literature:

Multi-step reaction with 4 steps

1: 1) Mg / 1) THF, 15 min, reflux, 2) 2 h

2: 70 percent / pyridinium chlorochromate, NaOAc / CH₂Cl₂ / 0.5 h / Ambient temperature

3: 92 percent / PhSeSePh, Et₄NBr / acetonitrile; H₂O / 6 h / electrolysis

4: 54 percent / pyridinium chlorochromate, manganese sulfate / CH₂Cl₂ / 12 h / Ambient temperature

With manganese(II) sulfate; diphenyl diselenide; tetraethylammonium bromide; sodium acetate; magnesium; pyridinium chlorochromate; In dichloromethane; water; acetonitrile;

upstream raw materials:

2-methyl-1-propenylbromide

(R)-6-(tert-Butyl-dimethyl-silanyloxy)-6-furan-3-yl-3-methyl-hexanoic acid methyl ester

(4R,8RS)-1-(3'-Furyl)-8-hydroxy-4,8-dimethyl-6-nonen-1-one

furan-3-carboxaldehyde

Downstream raw materials:

(+)-S-myomontanone