N-[(11bS)-2,6-bis[3,5-bis(trifluoromethyl)phenyl]-4-oxidodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoro-Methanesulfonamide

Base Information

Chemical Name:N-[(11bS)-2,6-bis[3,5-bis(trifluoromethyl)phenyl]-4-oxidodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoro-Methanesulfonamide
CAS No.:1236120-02-7
Molecular Formula:C₃₇H₁₇F₁₅NO₅PS
Molecular Weight:903.561
Hs Code.:
Mol file:1236120-02-7.mol

N-[(11bS)-2,6-bis[3,5-bis(trifluoromethyl)phenyl]-4-oxidodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoro-Methanesulfonamide

Synonyms:

Suppliers and Price of N-[(11bS)-2,6-bis[3,5-bis(trifluoromethyl)phenyl]-4-oxidodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoro-Methanesulfonamide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

TRC
(S)-3,3''-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1''-binaphthyl-2,2''-diyl-N-triflylphosphoramide
1mg
$ 45.00

Total 5 raw suppliers

Chemical Property of N-[(11bS)-2,6-bis[3,5-bis(trifluoromethyl)phenyl]-4-oxidodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoro-Methanesulfonamide

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

(S)-3,3''-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1''-binaphthyl-2,2''-diyl-N-triflylphosphoramide ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of N-[(11bS)-2,6-bis[3,5-bis(trifluoromethyl)phenyl]-4-oxidodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoro-Methanesulfonamide

There total 8 articles about N-[(11bS)-2,6-bis[3,5-bis(trifluoromethyl)phenyl]-4-oxidodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoro-Methanesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: (S)-3,3’-bis(3,5-bis(trifluoromethyl)phenyl)-[1,1’-binaphthalene]-2,2’-diol

: 28048-16-0
(N-trichlorophosphoranylidene)trifluoromethanesulfonamide

: 1236120-02-7
(S)-[3,3’-di(3,5-bis(trifluoromethyl)phenyl)-1,1’-binaphthalen-2,2’-yl]-N-triflyl phosphorami

Guidance literature:: (S)-3,3’-bis(3,5-bis(trifluoromethyl)phenyl)-[1,1’-binaphthalene]-2,2’-diol; (N-trichlorophosphoranylidene)trifluoromethanesulfonamide; With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; Inert atmosphere;

With water; In dichloromethane; at 20 ℃; for 0.166667h; Inert atmosphere;
DOI:10.1055/s-0036-1588782

Reference yield: 81.0%

: (S)-3,3'-bis[3,5-di(trifluoromethyl)phenyl]-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2,2'-diyl-N-trifyl-phosphoramide

: 1236120-02-7
(S)-[3,3’-di(3,5-bis(trifluoromethyl)phenyl)-1,1’-binaphthalen-2,2’-yl]-N-triflyl phosphorami

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In chlorobenzene; at 145 ℃; for 15h; Sealed tube;
DOI:10.1021/acs.orglett.5b01754

Reference yield: 20.0%

: 421-85-2
Trifluoromethanesulfonamide

: 3,3'-bis-(3,5-bis-trifluoromethyl-phenyl)-[1,1']binaphthalenyl-2,2'-diol

: 1236120-02-7
C₃₇H₁₇F₁₅NO₅PS

Guidance literature:: 3,3'-bis-(3,5-bis-trifluoromethyl-phenyl)-[1,1']binaphthalenyl-2,2'-diol; With dmap; triethylamine; trichlorophosphate; In dichloromethane; at 0 - 20 ℃; for 2h; Inert atmosphere;

Trifluoromethanesulfonamide; In dichloromethane; at 90 ℃; for 16h; Inert atmosphere;
DOI:10.1002/chem.202003783