d33-hexadecanethiol

Base Information

• Chemical Name: d33-hexadecanethiol
• CAS No.: 218956-22-0
• Molecular Formula: C₁₆H₃₄S
• Molecular Weight: 291.25
• Mol file: 218956-22-0.mol

Synonyms:

Chemical Property of d33-hexadecanethiol

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

1-Hexadecane-d33-thiol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: 1-Hexadecane-d33-thiol (CAS# 218956-22-0) is a useful isotopically labeled research compound.

Technology Process of d33-hexadecanethiol

There total 3 articles about d33-hexadecanethiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

[D33]-hexadecyl bromide (284474-41-5,1219805-65-8,284474-40-4) → d33-hexadecanethiol (218956-22-0)

Guidance literature:

[D₃₃]-hexadecyl bromide; With sodium thiosulfate; In ethanol; Heating;

With hydrogenchloride;

DOI:10.1021/jp031273u

Reference yield:

palmitic acid-d31 (39756-30-4,272442-14-5,285979-77-3,358730-99-1,78387-70-9,1219802-61-5) → d33-hexadecanethiol (218956-22-0)

Guidance literature:

Multi-step reaction with 3 steps

1.1: 98 percent / LiAlD₄ / tetrahydrofuran

2.1: 83 percent / aq. HBr / Heating

3.1: Na₂S₂O₃ / ethanol / Heating

3.2: 94 percent / aq. HCl

With lithium aluminium deuteride; hydrogen bromide; sodium thiosulfate; In tetrahydrofuran; ethanol;

DOI:10.1021/jp031273u

Reference yield:

1-hexadecyl-d33-ol (284474-73-3,1219799-18-4,1219799-21-9) → d33-hexadecanethiol (218956-22-0)

Guidance literature:

Multi-step reaction with 2 steps

1.1: 83 percent / aq. HBr / Heating

2.1: Na₂S₂O₃ / ethanol / Heating

2.2: 94 percent / aq. HCl

With hydrogen bromide; sodium thiosulfate; In ethanol;

DOI:10.1021/jp031273u

upstream raw materials:

[D₃₃]-hexadecyl bromide

palmitic acid-d31

1-hexadecyl-d33-ol