4-Chloracetoxy-1-hydroxy-2,2,6,6-tetramethylpiperidin

Base Information

• Chemical Name: 4-Chloracetoxy-1-hydroxy-2,2,6,6-tetramethylpiperidin
• CAS No.: 36775-17-4
• Molecular Formula: C₁₁H₂₀ClNO₃
• Molecular Weight: 249.738
• Mol file: 36775-17-4.mol

Synonyms:

Chemical Property of 4-Chloracetoxy-1-hydroxy-2,2,6,6-tetramethylpiperidin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-Chloracetoxy-1-hydroxy-2,2,6,6-tetramethylpiperidin

There total 3 articles about 4-Chloracetoxy-1-hydroxy-2,2,6,6-tetramethylpiperidin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloroacetic acid 2,2,6,6-tetramethyl-1-oxy-piperidin-4-yl ester (35356-60-6) → 4-Chloracetoxy-1-hydroxy-2,2,6,6-tetramethylpiperidin (36775-17-4)

Guidance literature:

With phenylhydrazine; In chloroform-d1;

DOI:10.1055/s-2005-862396

Reference yield:

TEMPOL (45985-24-8,2226-96-2) → 4-Chloracetoxy-1-hydroxy-2,2,6,6-tetramethylpiperidin (36775-17-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 92 percent / DMAP; DCC / CH₂Cl₂ / 12 h / 20 °C

2: phenylhydrazine / CDCl₃

With dmap; phenylhydrazine; dicyclohexyl-carbodiimide; In chloroform-d1; dichloromethane;

DOI:10.1055/s-2005-862396

Reference yield:

→ 4-Chloracetoxy-1-hydroxy-2,2,6,6-tetramethylpiperidin (36775-17-4)

Guidance literature:

Radikal III, Phenylhydrazin;

DOI:10.1007/BF00481109

upstream raw materials:

chloroacetic acid 2,2,6,6-tetramethyl-1-oxy-piperidin-4-yl ester

TEMPOL