α-anomer of trideca-O-methyltellimagrandin-I

Base Information

• Chemical Name: α-anomer of trideca-O-methyltellimagrandin-I
• CAS No.: 82220-63-1
• Molecular Formula: C₄₇H₅₂O₂₂
• Molecular Weight: 968.917
• Mol file: 82220-63-1.mol

Synonyms:

Chemical Property of α-anomer of trideca-O-methyltellimagrandin-I

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of α-anomer of trideca-O-methyltellimagrandin-I

There total 6 articles about α-anomer of trideca-O-methyltellimagrandin-I which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tellimagrandin I (30737-92-9,118014-28-1,118014-29-2) + dimethyl sulfate (77-78-1) → tridecamethyltellimagrandin (β-anomer) (82220-63-1) + α-anomer of trideca-O-methyltellimagrandin-I (82220-63-1)

Guidance literature:

With potassium carbonate; In acetone; Yield given. Yields of byproduct given; 1) room temperature, overnight, 2) reflux, 2.5 h;

DOI:10.1248/cpb.39.1157

Reference yield:

tellimagrandin I (30737-92-9,118014-28-1,118014-29-2) + dimethyl sulfate (77-78-1) → tridecamethyltellimagrandin (β-anomer) (82220-63-1) + α-anomer of trideca-O-methyltellimagrandin-I (82220-63-1)

Guidance literature:

With potassium carbonate; In acetone; Yield given. Yields of byproduct given; 1) room temperature, overnight, 2) reflux, 2.5 h;

DOI:10.1248/cpb.39.1157

Reference yield:

gemin A (82220-61-9) + dimethyl sulfate (77-78-1) → α-anomer of trideca-O-methyltellimagrandin-I (82220-63-1) + β-anomer of trideca-O-methylpedunculagin (7045-43-4,79814-67-8,79814-68-9) + heptadeca-O-methylcoriariin B monomethyl ester (82220-64-2) + O-nonacosamethyl gemin A

Guidance literature:

With potassium carbonate; In acetone; for 12h; Further byproducts given; Heating;

DOI:10.1039/c39820000351

upstream raw materials:

tellimagrandin I

dimethyl sulfate

gemin A