methyl 2-O-benzyl-3-deoxy-5S-deutero-α-L-arabinopyranose

Base Information

Chemical Name:methyl 2-O-benzyl-3-deoxy-5S-deutero-α-L-arabinopyranose
CAS No.:1279711-62-4
Molecular Formula:C₁₃H₁₈O₄
Molecular Weight:239.276
Hs Code.:

Synonyms:

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Chemical Property of methyl 2-O-benzyl-3-deoxy-5S-deutero-α-L-arabinopyranose

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Technology Process of methyl 2-O-benzyl-3-deoxy-5S-deutero-α-L-arabinopyranose

There total 5 articles about methyl 2-O-benzyl-3-deoxy-5S-deutero-α-L-arabinopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₂₂H₂₆O₆

: C₁₃H₁₇⁽²⁾HO₄

: 1279711-62-4
methyl 2-O-benzyl-3-deoxy-5S-deutero-α-L-arabinopyranose

Guidance literature:: Multi-step reaction with 5 steps

1.1: acetic acid / tetrahydrofuran; water / 45 °C

2.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 1 h / 20 °C

3.1: DMF dineopentyl acetal / N,N-dimethyl-formamide / 2 h / 200 °C / high-pressure vessel

4.1: 3,3-dimethyldioxirane / dichloromethane; acetone / 48 h / -55 °C

5.1: lithium aluminium deuteride / tetrahydrofuran; diethyl ether / 18 h / -78 - 20 °C

5.2: -55 - 20 °C

With lithium aluminium deuteride; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; DMF dineopentyl acetal; 3,3-dimethyldioxirane; acetic acid; In tetrahydrofuran; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; acetone;
DOI:10.1021/jo102382r

Reference yield:

: C₁₄H₁₈O₆

: C₁₃H₁₇⁽²⁾HO₄

: 1279711-62-4
methyl 2-O-benzyl-3-deoxy-5S-deutero-α-L-arabinopyranose

Guidance literature:: Multi-step reaction with 3 steps

1.1: DMF dineopentyl acetal / N,N-dimethyl-formamide / 2 h / 200 °C / high-pressure vessel

2.1: 3,3-dimethyldioxirane / dichloromethane; acetone / 48 h / -55 °C

3.1: lithium aluminium deuteride / tetrahydrofuran; diethyl ether / 18 h / -78 - 20 °C

3.2: -55 - 20 °C

With lithium aluminium deuteride; DMF dineopentyl acetal; 3,3-dimethyldioxirane; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide; acetone;
DOI:10.1021/jo102382r

Reference yield:

: 1279711-49-7
methyl 2-O-benzyl-3,4-dideoxy-α-pent-4-enopyranoside

: C₁₃H₁₇⁽²⁾HO₄

: 1279711-62-4
methyl 2-O-benzyl-3-deoxy-5S-deutero-α-L-arabinopyranose

Guidance literature:: Multi-step reaction with 2 steps

1.1: 3,3-dimethyldioxirane / dichloromethane; acetone / 48 h / -55 °C

2.1: lithium aluminium deuteride / tetrahydrofuran; diethyl ether / 18 h / -78 - 20 °C

2.2: -55 - 20 °C

With lithium aluminium deuteride; 3,3-dimethyldioxirane; In tetrahydrofuran; diethyl ether; dichloromethane; acetone;
DOI:10.1021/jo102382r