cis-[Rh(PPh₃)2(benzylamine)2]PF₆

Base Information

• Chemical Name: cis-[Rh(PPh₃)2(benzylamine)2]PF₆
• CAS No.: 728023-75-4
• Molecular Formula: C₅₀H₄₈N₂P₂Rh*F₆P
• Molecular Weight: 986.762
• Mol file: 728023-75-4.mol

Synonyms:

Chemical Property of cis-[Rh(PPh₃)2(benzylamine)2]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of cis-[Rh(PPh₃)2(benzylamine)2]PF₆

There total 2 articles about cis-[Rh(PPh₃)2(benzylamine)2]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cis,trans,cis-[Rh(H)2(PPh3)2(benzylamine)2]PF6 (790673-68-6) → cis-[Rh(PPh3)2(benzylamine)2]PF6 (728023-75-4)

Guidance literature:

In dichloromethane-d2; byproducts: H2; under Ar; Rh complex dissolved in CD2Cl2; reversible react.;

DOI:10.1021/ic049227b

Reference yield:

cis,trans,cis-[Rh(H)2(PPh3)2(benzylamine)2]PF6 (790673-68-6) → cis,trans,cis-[Rh(H)2(PPh3)2(benzylamine)(methanol)]PF6 + cis-[Rh(PPh3)2(benzylamine)2]PF6 (728023-75-4)

Guidance literature:

In d⁽⁴⁾-methanol; byproducts: H2; under Ar; Rh complex dissolved in CD3OD; reversible react.; not isolated; monitored by (31)P NMR spectra; mixt. of initial complex and two resultant complexes obtained;

DOI:10.1021/ic049227b

upstream raw materials:

cis,trans,cis-[Rh(H)2(PPh₃)2(benzylamine)2]PF₆