[1-(C₅Me₅)-1,1-(H)2-arachno-1-IrB₂H₄-2-(PMePh₂)]

Base Information

• Chemical Name: [1-(C₅Me₅)-1,1-(H)2-arachno-1-IrB₂H₄-2-(PMePh₂)]
• CAS No.: 691015-15-3
• Molecular Formula: C₂₃H₃₄B₂IrP
• Molecular Weight: 555.339
• Mol file: 691015-15-3.mol

Synonyms:

Chemical Property of [1-(C₅Me₅)-1,1-(H)2-arachno-1-IrB₂H₄-2-(PMePh₂)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [1-(C₅Me₅)-1,1-(H)2-arachno-1-IrB₂H₄-2-(PMePh₂)]

There total 2 articles about [1-(C₅Me₅)-1,1-(H)2-arachno-1-IrB₂H₄-2-(PMePh₂)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

arachno-1-((η5-pentamethylcyclopentadienyl)IrH)B4H9 (296279-15-7) + diphenyl(methyl)phosphine (1486-28-8) → [1-(C5Me5)-1,1-(H)2-arachno-1-IrB2H4-2-(PMePh2)] (691015-15-3) + methyldiphenylphosphine borane complex

Guidance literature:

In tetrahydrofuran; benzene-d6; (Ar); standard Schlenk technique; PMePh2 in THF was added to soln. of Ircomplex in C6D6 at room temp. in NMR tube; transferred to Schlenk flask ; evapd. (vac.); kept in refrigerator for 2 d; NMR monitoring; thin-layer chromd. (silica gel, CH2Cl2/hexane, 1/1); elem. anal.;

DOI:10.1021/om049960a

Reference yield:

[1-(C5Me5)-1-(H)-arachno-1-IrB3H7] + diphenyl(methyl)phosphine (1486-28-8) → [1-(C5Me5)-1,1-(H)2-arachno-1-IrB2H4-2-(PMePh2)] (691015-15-3)

Guidance literature:

In benzene-d6; (Ar); standard Schlenk technique; PMePh2 (5 equiv.) was added to soln. of Ir complex in C6D6 at room temp. in NMR tube; NMR monitoring;

DOI:10.1021/om049960a

upstream raw materials:

arachno-1-((η5-pentamethylcyclopentadienyl)IrH)B4H9

diphenyl(methyl)phosphine