meso-1,2-bis(N,N-diphenylaminobromophosphino)-1,2-dicarba-closo-dodecaborane

Base Information

Chemical Name:meso-1,2-bis(N,N-diphenylaminobromophosphino)-1,2-dicarba-closo-dodecaborane
CAS No.:1165474-66-7
Molecular Formula:C₂₆H₃₀B₁₀Cl₂N₂P₂
Molecular Weight:611.501
Hs Code.:

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Suppliers and Price of meso-1,2-bis(N,N-diphenylaminobromophosphino)-1,2-dicarba-closo-dodecaborane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of meso-1,2-bis(N,N-diphenylaminobromophosphino)-1,2-dicarba-closo-dodecaborane

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Technology Process of meso-1,2-bis(N,N-diphenylaminobromophosphino)-1,2-dicarba-closo-dodecaborane

There total 1 articles about meso-1,2-bis(N,N-diphenylaminobromophosphino)-1,2-dicarba-closo-dodecaborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

: 109-72-8,29786-93-4
n-butyllithium

: 16872-09-6
1,2-dicarba-closo-dodecaborane⁽¹²⁾

: 4614-90-8
Diphenylamino-phosphordichlorid

: 108-88-3,15644-74-3,16713-13-6
toluene

: 1165474-66-7,1165474-73-6
meso-1,2-bis(N,N-diphenylaminobromophosphino)-1,2-dicarba-closo-dodecaborane

: rac-1,2-bis(N,N-diphenylaminobromophosphino)-1,2-dicarba-closo-dodecaborane*toluene

Guidance literature:: In diethyl ether; hexane; (N2); addn. of hexane soln. of butyllithium to ethereal soln. of carborane deriv. at 0°C, warming to room temp., stirring for 2 h, addn. to cold ethereal soln. of phosphine deriv., stirring at room temp. overnight; filtration through silica gel, evapn., dissolving in pentane, fractionalcrystn. by cooling to 4°C, elem. anal.;
DOI:10.1021/ic900443c