dichloro(2,6-bis(tert-butylaminomethyl)pyridine)(triphenyl phosphite)ruthenium(II)

Base Information

• Chemical Name: dichloro(2,6-bis(tert-butylaminomethyl)pyridine)(triphenyl phosphite)ruthenium(II)
• CAS No.: 264625-90-3
• Molecular Formula: C₃₃H₄₂Cl₂N₃O₃PRu
• Molecular Weight: 731.665
• Mol file: 264625-90-3.mol

Synonyms:

Chemical Property of dichloro(2,6-bis(tert-butylaminomethyl)pyridine)(triphenyl phosphite)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of dichloro(2,6-bis(tert-butylaminomethyl)pyridine)(triphenyl phosphite)ruthenium(II)

There total 2 articles about dichloro(2,6-bis(tert-butylaminomethyl)pyridine)(triphenyl phosphite)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dichloro(2,6-bis(tert-butylaminomethyl)pyridine)(triphenyl phosphite)ruthenium(II) → dichloro(2,6-bis(tert-butylaminomethyl)pyridine)(triphenyl phosphite)ruthenium(II) (264625-90-3)

Guidance literature:

In acetone; under Ar; isomerization on heating to reflux in acetone soln. for 2 h; detd. by (1) H NMR spectra;

DOI:10.1021/ic990737t

Reference yield:

triphenyl phosphite (101-02-0) + dichloro(2,6-bis(tert-butylaminomethyl)pyridine)(triphenylphosphine)ruthenium(II) + dichloro(2,6-bis(tert-butylaminomethyl)pyridine)(triphenylphosphine)ruthenium(II) → dichloro(2,6-bis(tert-butylaminomethyl)pyridine)(triphenyl phosphite)ruthenium(II) (264625-90-3) + dichloro(2,6-bis(tert-butylaminomethyl)pyridine)(triphenyl phosphite)ruthenium(II)

Guidance literature:

In tetrahydrofuran; byproducts: triphenylphisphine; under Ar; soln. of Ru complex and ligand (molar ratio 1:2) in THF heated to reflux for 15 h; product represented mixt. of two isomers in A:B=1:4 ratio, total yield 81%; solvent evapd.; ppt. collected on glass frit; washed with Et2O; dried in vac.;

DOI:10.1021/ic990737t

upstream raw materials:

triphenyl phosphite