Octanoic acid (3R,3aS,4R,6R,6aS,7R,8R,9bR)-6-acetoxy-3,3a-dihydroxy-3,6,9-trimethyl-8-((Z)-2-methyl-but-2-enoyloxy)-2-oxo-4-((R)-2-phenyl-butyryloxy)-2,3,3a,4,5,6,6a,7,8,9b-decahydro-azuleno[4,5-b]furan-7-yl ester

Base Information

• Chemical Name: Octanoic acid (3R,3aS,4R,6R,6aS,7R,8R,9bR)-6-acetoxy-3,3a-dihydroxy-3,6,9-trimethyl-8-((Z)-2-methyl-but-2-enoyloxy)-2-oxo-4-((R)-2-phenyl-butyryloxy)-2,3,3a,4,5,6,6a,7,8,9b-decahydro-azuleno[4,5-b]furan-7-yl ester
• CAS No.: 84074-12-4
• Molecular Formula: C₄₀H₅₄O₁₂
• Molecular Weight: 726.862
• Mol file: 84074-12-4.mol

Synonyms:

Chemical Property of Octanoic acid (3R,3aS,4R,6R,6aS,7R,8R,9bR)-6-acetoxy-3,3a-dihydroxy-3,6,9-trimethyl-8-((Z)-2-methyl-but-2-enoyloxy)-2-oxo-4-((R)-2-phenyl-butyryloxy)-2,3,3a,4,5,6,6a,7,8,9b-decahydro-azuleno[4,5-b]furan-7-yl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Octanoic acid (3R,3aS,4R,6R,6aS,7R,8R,9bR)-6-acetoxy-3,3a-dihydroxy-3,6,9-trimethyl-8-((Z)-2-methyl-but-2-enoyloxy)-2-oxo-4-((R)-2-phenyl-butyryloxy)-2,3,3a,4,5,6,6a,7,8,9b-decahydro-azuleno[4,5-b]furan-7-yl ester

There total 1 articles about Octanoic acid (3R,3aS,4R,6R,6aS,7R,8R,9bR)-6-acetoxy-3,3a-dihydroxy-3,6,9-trimethyl-8-((Z)-2-methyl-but-2-enoyloxy)-2-oxo-4-((R)-2-phenyl-butyryloxy)-2,3,3a,4,5,6,6a,7,8,9b-decahydro-azuleno[4,5-b]furan-7-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-phenylbutyric anhydride (1519-21-7) + Octanoic acid (3R,3aS,4R,6R,6aS,7R,8R,9bR)-6-acetoxy-3,3a,4-trihydroxy-3,6,9-trimethyl-8-((Z)-2-methyl-but-2-enoyloxy)-2-oxo-2,3,3a,4,5,6,6a,7,8,9b-decahydro-azuleno[4,5-b]furan-7-yl ester (80048-99-3) → Octanoic acid (3R,3aS,4R,6R,6aS,7R,8R,9bR)-6-acetoxy-3,3a-dihydroxy-3,6,9-trimethyl-8-((Z)-2-methyl-but-2-enoyloxy)-2-oxo-4-((R)-2-phenyl-butyryloxy)-2,3,3a,4,5,6,6a,7,8,9b-decahydro-azuleno[4,5-b]furan-7-yl ester (84074-12-4) + Octanoic acid (3R,3aS,4R,6R,6aS,7R,8R,9bR)-6-acetoxy-3,3a-dihydroxy-3,6,9-trimethyl-8-((Z)-2-methyl-but-2-enoyloxy)-2-oxo-4-((S)-2-phenyl-butyryloxy)-2,3,3a,4,5,6,6a,7,8,9b-decahydro-azuleno[4,5-b]furan-7-yl ester (84074-11-3)

Guidance literature:

dmap; In dichloromethane; at -78 ℃; for 216h; Product distribution; var. times and temperatures, var. product distribution;

DOI:10.1021/jo00151a029

upstream raw materials:

2-phenylbutyric anhydride

Octanoic acid (3R,3aS,4R,6R,6aS,7R,8R,9bR)-6-acetoxy-3,3a,4-trihydroxy-3,6,9-trimethyl-8-((Z)-2-methyl-but-2-enoyloxy)-2-oxo-2,3,3a,4,5,6,6a,7,8,9b-decahydro-azuleno[4,5-b]furan-7-yl ester