Pentacarbonyl[(p-methoxyphenyl)(phenyl)thioketon]wolfram

Base Information

• Chemical Name: Pentacarbonyl[(p-methoxyphenyl)(phenyl)thioketon]wolfram
• CAS No.: 67677-47-8
• Molecular Formula: C₁₉H₁₂O₆SW
• Molecular Weight: 552.217
• Mol file: 67677-47-8.mol

Synonyms:

Chemical Property of Pentacarbonyl[(p-methoxyphenyl)(phenyl)thioketon]wolfram

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pentacarbonyl[(p-methoxyphenyl)(phenyl)thioketon]wolfram

There total 3 articles about Pentacarbonyl[(p-methoxyphenyl)(phenyl)thioketon]wolfram which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

[W(CO)5CPh(C6H4-p-OCH3)] (76096-47-4) + methyl thioisocyanate (556-61-6) → Pentacarbonyl[(p-methoxyphenyl)(phenyl)thioketon]wolfram (67677-47-8)

Guidance literature:

In pentane; stirred under N2 at room temp. for 6 h; cooled to -20°C on silica gel, chromy. (SiO2, CH2Cl2/pentane, N2), evapd. in vac. at -10°C, recrystd. (pentane), elem. anal.;

Reference yield: 36.0%

[W(CO)5CPh(C6H4-p-OCH3)] (76096-47-4) + phenyl isothiocyanate (103-72-0) → Pentacarbonyl[(p-methoxyphenyl)(phenyl)thioketon]wolfram (67677-47-8)

Guidance literature:

In pentane; stirred under N2 at room temp. for 36 h; cooled to -20°C on silica gel, chromy. (SiO2, CH2Cl2/pentane, N2), evapd. in vac. at -10°C, recrystd. (pentane), elem. anal.;

Reference yield: 27.0%

sulfur (10544-50-0) + [W(CO)5CPh(C6H4-p-OCH3)] (76096-47-4) → Pentacarbonyl[(p-methoxyphenyl)(phenyl)thioketon]wolfram (67677-47-8)

Guidance literature:

In pentane; byproducts: W(CO)6; soln. was stirred at room temp. for 15 h under N2; oil ppt. extd. with pentane, ext. chromd. at -10°C, evapd., recrystd. from pentane; elem. anal.;

DOI:10.1016/S0022-328X(00)83023-5

upstream raw materials:

[W(CO)5CPh(C₆H₄-p-OCH₃)]

methyl thioisocyanate

sulfur

phenyl isothiocyanate