1-ferrocenyl-6-(4-bromophenyl)dodecamethylhexasilane

Base Information

• Chemical Name: 1-ferrocenyl-6-(4-bromophenyl)dodecamethylhexasilane
• CAS No.: 352462-71-6
• Molecular Formula: C₂₈H₄₉BrFeSi₆
• Molecular Weight: 689.961
• Mol file: 352462-71-6.mol

Synonyms:

Chemical Property of 1-ferrocenyl-6-(4-bromophenyl)dodecamethylhexasilane

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of 1-ferrocenyl-6-(4-bromophenyl)dodecamethylhexasilane

There total 1 articles about 1-ferrocenyl-6-(4-bromophenyl)dodecamethylhexasilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

lithiumferrocene (1271-15-4) + 1-chloro-6-(4-bromophenyl)dodecamethylhexasilane (352462-70-5) → 1-ferrocenyl-6-(4-bromophenyl)dodecamethylhexasilane (352462-71-6)

Guidance literature:

In tetrahydrofuran; under N2 atm. soln. ferrocenyllithium in THF was added slowly to stirredsoln. 1-chloro-6-(4-bromophenyl)dodecamethylhexasilane in THF at room t emp., react. mixt. was refluxed overnight; solvent was stripped off, residual ferrocene was removed by sublimation,residue was dissolved in Et2O, aq. NH4Cl was added, org. layer was drie d over Na2SO4 and concd., chromy. on silica using heptane-toluene (95:5)as eluent;

DOI:10.1016/S0022-328X(01)00743-4

upstream raw materials:

lithiumferrocene

1-chloro-6-(4-bromophenyl)dodecamethylhexasilane