Ru₃(CO)9(P(OCH₂)3CC₂H₅)(CNC(CH₃)3)(As(C₆H₅)3)

Base Information

• Chemical Name: Ru₃(CO)9(P(OCH₂)3CC₂H₅)(CNC(CH₃)3)(As(C₆H₅)3)
• CAS No.: 86292-15-1
• Molecular Formula: C₃₈H₃₅AsNO₁₂PRu₃
• Molecular Weight: 1106.8
• Mol file: 86292-15-1.mol

Synonyms:

Chemical Property of Ru₃(CO)9(P(OCH₂)3CC₂H₅)(CNC(CH₃)3)(As(C₆H₅)3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru₃(CO)9(P(OCH₂)3CC₂H₅)(CNC(CH₃)3)(As(C₆H₅)3)

There total 1 articles about Ru₃(CO)9(P(OCH₂)3CC₂H₅)(CNC(CH₃)3)(As(C₆H₅)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

Ru3(CO)11(As(C6H5)3)*C6H6 + tert-butylisonitrile (119072-55-8,7188-38-7) + ethriol phosphite (824-11-3) → Ru3(CO)9(P(OCH2)3CC2H5)(CNC(CH3)3)(As(C6H5)3) (86292-15-1) + Ru3(CO)9(P(OCH2)3CC2H5)2(CNC(CH3)3) (86292-09-3) + Ru3(CO)10(P(OCH2)3CC2H5)2 (86276-95-1) + Ru3(CO)10(P(OCH2)3CC2H5)(CNC(CH3)3) + Ru3(CO)11(P(OCH2)3CC2H5) (86276-94-0,117307-51-4)

Guidance literature:

With sodium diphenylketyl; In tetrahydrofuran; a THF soln. of Ph2CONa was added dropwise under N2 to a soln. of Ru3(CO)10(AsPh3) and P(OCH2)3CEt in THF at room temp., stirred for 15 min, t-BuNC was added, reaction was monitored by IR spectroscopy; solvent was removed, products were sepd. by preparative TLC and identified by spectral data; elem. anal. for the main product;

DOI:10.1016/0022-328X(83)85174-2

upstream raw materials:

tert-butylisonitrile

ethriol phosphite