bis(triphenylphosphine)iminium hexacarbonylniobate(-I)

Base Information

• Chemical Name: bis(triphenylphosphine)iminium hexacarbonylniobate(-I)
• CAS No.: 82738-68-9
• Molecular Formula: C₆NbO₆*C₃₆H₃₀NP₂
• Molecular Weight: 799.557
• Mol file: 82738-68-9.mol

Synonyms:

Chemical Property of bis(triphenylphosphine)iminium hexacarbonylniobate(-I)

Chemical Property:

Purity/Quality:

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Technology Process of bis(triphenylphosphine)iminium hexacarbonylniobate(-I)

There total 1 articles about bis(triphenylphosphine)iminium hexacarbonylniobate(-I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

sodium hexacarbonylniobate*THF (15602-39-8) + bis(triphenylphosphine)iminium chloride (21050-13-5) → bis(triphenylphosphine)iminium hexacarbonylniobate(-I) (82738-68-9)

Guidance literature:

In dichloromethane; byproducts: NaCl; suspn. of Na(Nb(CO)6)*C4H8O in CH2Cl2 treated with (N(PPh3)2)Cl under Ar; ppt. filtered, added Et2O, pptd. by cooling to -30 °C, filtered,dried in vac.; elem. anal.;

DOI:10.1016/S0022-328X(00)85584-9

upstream raw materials:

sodium hexacarbonylniobate*THF

bis(triphenylphosphine)iminium chloride