(S)-tert-butyldimethyl((1-phenyltetradec-1-en-4-yl)oxy)silane

Base Information

Chemical Name:(S)-tert-butyldimethyl((1-phenyltetradec-1-en-4-yl)oxy)silane
CAS No.:1638142-40-1
Molecular Formula:C₂₆H₄₆OSi
Molecular Weight:402.736
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-tert-butyldimethyl((1-phenyltetradec-1-en-4-yl)oxy)silane

Chemical Property:

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Technology Process of (S)-tert-butyldimethyl((1-phenyltetradec-1-en-4-yl)oxy)silane

There total 4 articles about (S)-tert-butyldimethyl((1-phenyltetradec-1-en-4-yl)oxy)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 130404-09-0
(2S)-1,2-epoxydodecane

: 1638142-41-2
(S)-tert-butyldimethyl((1-phenyltetradec-1-en-4-yl)oxy)silane

: 1638142-40-1
(S)-tert-butyldimethyl((1-phenyltetradec-1-en-4-yl)oxy)silane

Guidance literature:: Multi-step reaction with 3 steps

1: sodium iodide; sodium acetate / ethyl acetate; acetic acid / 24 h / 20 °C / Inert atmosphere

2: 2,6-dimethylpyridine / dichloromethane / 1.5 h / -78 °C / Inert atmosphere

3: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; N-Methyldicyclohexylamine; α,α,α-trifluorotoluene / 15 h / 100 °C / Glovebox; Sealed tube

With 2,6-dimethylpyridine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; α,α,α-trifluorotoluene; N-Methyldicyclohexylamine; sodium acetate; sodium iodide; In dichloromethane; acetic acid; ethyl acetate; 3: |Heck Reaction;
DOI:10.1002/anie.201311323

Reference yield:

: 2855-19-8
Decyl-oxiran

: 1638142-41-2
(S)-tert-butyldimethyl((1-phenyltetradec-1-en-4-yl)oxy)silane

: 1638142-40-1
(S)-tert-butyldimethyl((1-phenyltetradec-1-en-4-yl)oxy)silane

Guidance literature:: Multi-step reaction with 4 steps

1: (acetao)(aqua)(S,S)-N,N′-bis(3,5-di-tert-butylsalicylidene-1,2-cyclohexanediamino)-cobalt(III); acetic acid / toluene; isopropyl alcohol / 24 h / 20 °C / Inert atmosphere

2: sodium iodide; sodium acetate / ethyl acetate; acetic acid / 24 h / 20 °C / Inert atmosphere

3: 2,6-dimethylpyridine / dichloromethane / 1.5 h / -78 °C / Inert atmosphere

4: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; N-Methyldicyclohexylamine; α,α,α-trifluorotoluene / 15 h / 100 °C / Glovebox; Sealed tube

With 2,6-dimethylpyridine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; (acetao)(aqua)(S,S)-N,N′-bis(3,5-di-tert-butylsalicylidene-1,2-cyclohexanediamino)-cobalt(III); α,α,α-trifluorotoluene; N-Methyldicyclohexylamine; sodium acetate; acetic acid; sodium iodide; In dichloromethane; acetic acid; ethyl acetate; isopropyl alcohol; toluene; 4: |Heck Reaction;
DOI:10.1002/anie.201311323

Reference yield:

: C₁₂H₂₅IO

: 1638142-41-2
(S)-tert-butyldimethyl((1-phenyltetradec-1-en-4-yl)oxy)silane

: 1638142-40-1
(S)-tert-butyldimethyl((1-phenyltetradec-1-en-4-yl)oxy)silane

Guidance literature:: Multi-step reaction with 2 steps

1: 2,6-dimethylpyridine / dichloromethane / 1.5 h / -78 °C / Inert atmosphere

2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; N-Methyldicyclohexylamine; α,α,α-trifluorotoluene / 15 h / 100 °C / Glovebox; Sealed tube

With 2,6-dimethylpyridine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; α,α,α-trifluorotoluene; N-Methyldicyclohexylamine; In dichloromethane; 2: |Heck Reaction;
DOI:10.1002/anie.201311323