Mo(CO)5[PPh₂(CH₂)4OAlEt₂]

Base Information

• Chemical Name: Mo(CO)5[PPh₂(CH₂)4OAlEt₂]
• CAS No.: 85883-65-4
• Molecular Formula: C₂₅H₂₈AlMoO₆P
• Molecular Weight: 578.389
• Mol file: 85883-65-4.mol

Synonyms:

Chemical Property of Mo(CO)5[PPh₂(CH₂)4OAlEt₂]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Mo(CO)5[PPh₂(CH₂)4OAlEt₂]

There total 2 articles about Mo(CO)5[PPh₂(CH₂)4OAlEt₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Mo(CO)5(PPh2H) (18399-61-6) → Mo(CO)5[PPh2(CH2)4OAlEt2] (85883-65-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 1,4-dioxane

2: tetrahydrofuran

In tetrahydrofuran; 1,4-dioxane;

DOI:10.1021/om50003a011

Reference yield:

Mo(CO)5PPh2K*dioxane (85883-56-3) + diethylaluminum bromide (760-19-0) → Mo(CO)5[PPh2(CH2)4OAlEt2] (85883-65-4)

Guidance literature:

In tetrahydrofuran; byproducts: KBr; hexane or toluene soln. of AlBrEt2 was added to stirred suspn. of Mo complex in THF under vac. at -78°C; slow warming to room temp. (2-3h); stirring at room temp. for 12-15 h; evapn., extn. with toluene, evapn., washing with hexane;

DOI:10.1021/om50003a011

upstream raw materials:

Mo(CO)5PPh₂K*dioxane

diethylaluminum bromide

Mo(CO)5(PPh2H)

Refernces