3-C3H5)Ph2P(CH2)4PPh2>(+)ClO4(-)

Base Information

• Chemical Name: 3-C3H5)Ph2P(CH2)4PPh2>(+)ClO4(-)
• CAS No.: 92342-85-3
• Molecular Formula: C₃₁H₃₃P₂Pd*ClO₄
• Molecular Weight: 673.421
• Mol file: 92342-85-3.mol

Synonyms:

Chemical Property of 3-C3H5)Ph2P(CH2)4PPh2>(+)ClO4(-)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 3-C3H5)Ph2P(CH2)4PPh2>(+)ClO4(-)

There total 1 articles about 3-C3H5)Ph2P(CH2)4PPh2>(+)ClO4(-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[PdCl(η(3)-allyl)]2 + sodium perchlorate + 1,4-di(diphenylphosphino)-butane (7688-25-7) → 3-C3H5)Ph2P(CH2)4PPh2>(+)ClO4(-) (92342-85-3)

Guidance literature:

With C₆H₅CH₂N(C₂H₅)3Br; In dichloromethane; water; addn. of aq. soln. of NaClO4 to mixt. of Pd-complex and org. ligand in CH2Cl2; subsequent addn. of PhCH2NEt3Br in H2O; stirring at ambient temp. for 3 h;; the CH2Cl2 layer was sepd., washed with water and dried; evapn.; recrystn. from CH2Cl2/THF; drying at room temp. under vac. (1 mmHg); elem. anal.;

DOI:10.1246/cl.1986.157

upstream raw materials:

1,4-di(diphenylphosphino)-butane