N-<(1SR)-(1,4,6/5)-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1SR)-(1,3,5/2,4,6)-2,3,4,5-tetrahydroxy-6-(hydroxymethyl)cyclohexylamine nonaacetate

Base Information

• Chemical Name: N-<(1SR)-(1,4,6/5)-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1SR)-(1,3,5/2,4,6)-2,3,4,5-tetrahydroxy-6-(hydroxymethyl)cyclohexylamine nonaacetate
• CAS No.: 90761-69-6
• Molecular Formula: C₃₂H₄₃NO₁₈
• Molecular Weight: 729.689
• Mol file: 90761-69-6.mol

Synonyms:

Chemical Property of N-<(1SR)-(1,4,6/5)-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1SR)-(1,3,5/2,4,6)-2,3,4,5-tetrahydroxy-6-(hydroxymethyl)cyclohexylamine nonaacetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-<(1SR)-(1,4,6/5)-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1SR)-(1,3,5/2,4,6)-2,3,4,5-tetrahydroxy-6-(hydroxymethyl)cyclohexylamine nonaacetate

There total 3 articles about N-<(1SR)-(1,4,6/5)-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1SR)-(1,3,5/2,4,6)-2,3,4,5-tetrahydroxy-6-(hydroxymethyl)cyclohexylamine nonaacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 7.8%

DL-4,7:5,6-di-O-isopropylidene-(1,4,6/5)-4,5,6-trihydroxy-3-hydroxymethyl-2-cyclohexenylamine (81692-19-5,86900-54-1,90025-02-8,109718-74-3,109718-75-4,132016-22-9) + DL-3,4-di-O-acetyl-1,2-anhydro-5,7-O-benzylidene-(1,2,4,6/3,5)-6-hydroxymethyl-1,2,3,4,5-cyclohexanepentol (77144-73-1,101758-36-5) → N-<(1SR)-(1,4,6/5)-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1SR)-(1,3,5/2,4,6)-2,3,4,5-tetrahydroxy-6-(hydroxymethyl)cyclohexylamine nonaacetate (90697-48-6,90761-69-6) + N-<(1SR)-(1,4,6/5)-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1RS)-(1,2,4/3,5,6)-2,3,4,6-tetrahydroxy-5-(hydroxymethyl)cyclohexylamine nonaacetate (81692-23-1,81739-21-1,114819-00-0) + N-<(1SR)-(1,4,6/5)-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1SR)-(1,2,4/3,5,6)-2,3,4,6-tetrahydroxy-5-(hydroxymethyl)cyclohexylamine nonaacetate (81692-23-1,81739-21-1,114819-00-0)

Guidance literature:

Yield given. Multistep reaction;

DOI:10.1021/jo00188a016

Reference yield: 6.0%

DL-4,7:5,6-di-O-isopropylidene-(1,4,6/5)-4,5,6-trihydroxy-3-hydroxymethyl-2-cyclohexenylamine (81692-19-5,86900-54-1,90025-02-8,109718-74-3,109718-75-4,132016-22-9) + DL-3,4-di-O-acetyl-1,2-anhydro-5,7-O-benzylidene-(1,2,4,6/3,5)-6-hydroxymethyl-1,2,3,4,5-cyclohexanepentol (77144-73-1,101758-36-5) → N-<(1SR)-(1,4,6/5)-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1RS)-(1,3,5/2,4,6)-2,3,4,5-tetrahydroxy-6-(hydroxymethyl)cyclohexylamine nonaacetate + N-<(1SR)-(1,4,6/5)-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1SR)-(1,3,5/2,4,6)-2,3,4,5-tetrahydroxy-6-(hydroxymethyl)cyclohexylamine nonaacetate (90697-48-6,90761-69-6) + N-<(1SR)-(1,4,6/5)-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1RS)-(1,2,4/3,5,6)-2,3,4,6-tetrahydroxy-5-(hydroxymethyl)cyclohexylamine nonaacetate (81692-23-1,81739-21-1,114819-00-0) + N-<(1SR)-(1,4,6/5)-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1SR)-(1,2,4/3,5,6)-2,3,4,6-tetrahydroxy-5-(hydroxymethyl)cyclohexylamine nonaacetate (81692-23-1,81739-21-1,114819-00-0)

Guidance literature:

Yield given. Multistep reaction;

DOI:10.1021/jo00188a016

Reference yield:

N-<(1SR)-4,7:5,6-di-O-isopropylidene-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1SR)-3,4-di-O-acetyl-5,7-O-benzylidene-(1,3,5/2,4,6)-2,3,4,5-tetrahydroxy-6-(hydroxymethyl)cyclohexylamine (81692-21-9,81739-19-7,90761-65-2,90761-66-3,148347-69-7) → N-<(1SR)-(1,4,6/5)-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1SR)-(1,3,5/2,4,6)-2,3,4,5-tetrahydroxy-6-(hydroxymethyl)cyclohexylamine nonaacetate (90697-48-6,90761-69-6)

Guidance literature:

With hydrogenchloride; 2.) acetylation;

DOI:10.1021/jo00188a016

upstream raw materials:

DL-4,7:5,6-di-O-isopropylidene-(1,4,6/5)-4,5,6-trihydroxy-3-hydroxymethyl-2-cyclohexenylamine

DL-3,4-di-O-acetyl-1,2-anhydro-5,7-O-benzylidene-(1,2,4,6/3,5)-6-hydroxymethyl-1,2,3,4,5-cyclohexanepentol

N-<(1SR)-4,7:5,6-di-O-isopropylidene-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1SR)-3,4-di-O-acetyl-5,7-O-benzylidene-(1,3,5/2,4,6)-2,3,4,5-tetrahydroxy-6-(hydroxymethyl)cyclohexylamine