chloro(η5-cyclopentadienyl)bis(dimethylphenylphosphane)iron

Base Information

Chemical Name:chloro(η5-cyclopentadienyl)bis(dimethylphenylphosphane)iron
CAS No.:97959-21-2
Molecular Formula:C₂₁H₂₇ClFeP₂
Molecular Weight:432.693
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Chemical Property of chloro(η5-cyclopentadienyl)bis(dimethylphenylphosphane)iron

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Technology Process of chloro(η5-cyclopentadienyl)bis(dimethylphenylphosphane)iron

There total 2 articles about chloro(η5-cyclopentadienyl)bis(dimethylphenylphosphane)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

: 95911-92-5
bis(dimethylphenylphosphino)iron(II) chloride

: 16733-97-4
cyclopentadienyllithium

: 97959-21-2
chloro(η5-cyclopentadienyl)bis(dimethylphenylphosphane)iron

Guidance literature:: In tetrahydrofuran; addn. of CpLi in dry THF to the Fe-complex in dry THF (under Ar), a violet soln. is obtained; removal of solvent after 48 h, addn. of pentane to the residue, filtration, drying, redissolving the solid in CH2Cl2, filtration, addn. of pentane to the filtrate, filtration of ppt., elem. anal.;

Reference yield: 25.0%

: 95911-92-5
bis(dimethylphenylphosphino)iron(II) chloride

: lithium cyclopentadienide

: 102-54-5,55404-68-7
ferrocene

: 97959-21-2
chloro(η5-cyclopentadienyl)bis(dimethylphenylphosphane)iron

Guidance literature:: In tetrahydrofuran; byproducts: LiCl; dropwise addn. of CpLi in THF to (PMe2Ph)2FeCl2 in THF under Ar at 20.dedree.C;; evapn. (vac.); dissolving in pentane; filtration; dissolving of the solid in CH2Cl2; filtration from LiCl; pptn. from filtrate by addn. of pentane, repeating operation; elem. anal.; Cp2Fe from the pentane filtrate and the THF distillate by sublimation;;