alpha-d-Glucopyranuronic acid, 1-(dihydrogen phosphate), potassium salt

Base Information

• Chemical Name: alpha-d-Glucopyranuronic acid, 1-(dihydrogen phosphate), potassium salt
• CAS No.: 71662-14-1
• Molecular Formula: C6H11 O10 P . x K
• Molecular Weight: 388.392
• Mol file: 71662-14-1.mol

Synonyms:alpha-d-Glucopyranuronic acid, 1-(dihydrogen phosphate), potassium salt

Chemical Property of alpha-d-Glucopyranuronic acid, 1-(dihydrogen phosphate), potassium salt

Chemical Property:

• PSA: 186.62000
• LogP: -4.34680

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of alpha-d-Glucopyranuronic acid, 1-(dihydrogen phosphate), potassium salt

There total 3 articles about alpha-d-Glucopyranuronic acid, 1-(dihydrogen phosphate), potassium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

α-D-Glucose 1-phosphate dipotassium salt (2040-69-9,6736-77-2,16419-25-3,19046-60-7,53823-71-5,71888-67-0,89798-48-1,91502-59-9,105751-36-8,133841-18-6) → Potassium α-D-glucopyranosiduronate 1-(dipotassium phosphate) (71662-14-1)

Guidance literature:

With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hydroxide; sodium hypochlorite; Dowex 5x8; In water; for 1.5h; other reagent;

DOI:10.1016/S0008-6215(97)00030-X

Reference yield:

α-D-Glucopyranosiduronic acid 1-(disodium phosphate) → Potassium α-D-glucopyranosiduronate 1-(dipotassium phosphate) (71662-14-1)

Guidance literature:

With potassium hydroxide; water; Yield given;

DOI:10.1055/s-1999-3464

Reference yield:

α-D-Glucopyranoside 1-(disodium phosphate) (56401-20-8) → Potassium α-D-glucopyranosiduronate 1-(dipotassium phosphate) (71662-14-1)

Guidance literature:

Multi-step reaction with 2 steps

1: TEMPO, carbonate buffer / 20 °C / electrochemical reaction: platinum foil anode and a graphite cathode, saturated calomel electrode as reference electrode (Hg/Hg₂Cl₂/saturated KCl in H₂O, +0.20 V vs. SCE), electrolysis at a potential of 0.53 V vs. SCE, charge consumption of 4.7 F/mol

2: KOH, H₂O

With 2,2,6,6-tetramethyl-piperidine-N-oxyl; potassium hydroxide; Carbonate buffer; water;

DOI:10.1055/s-1999-3464

upstream raw materials:

α-D-Glucose 1-phosphate dipotassium salt

α-D-Glucopyranoside 1-(disodium phosphate)

Refernces

• 1、 Schnatbaum, Karsten,Sch?fer, Hans J.. "Electroorganic synthesis 66: Selective anodic oxidation of carbohydrates mediated by TEMPO". . p. 864 - 872. Retrieved 2007/10/03.