[(η(5)-C5H5)Co]2S2C2B10H10

Base Information

• Chemical Name: [(η(5)-C5H5)Co]2S2C2B10H10
• CAS No.: 234756-10-6
• Molecular Formula: C₁₂H₂₀B₁₀Co₂S₂
• Molecular Weight: 454.519
• Mol file: 234756-10-6.mol

Synonyms:

Chemical Property of [(η(5)-C5H5)Co]2S2C2B10H10

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η(5)-C5H5)Co]2S2C2B10H10

There total 3 articles about [(η(5)-C5H5)Co]2S2C2B10H10 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

(η(5)-C5H5)Co(η(2)-S2C2B10H10) (234756-09-3) + phenylacetylene (536-74-3) → [(η(5)-C5H5)Co]2S2C2B10H10 (234756-10-6) + [(C5H5)Co(S(C2B10H9)SC(C6H5)CH2)] (948025-07-8) + [(C5H5)Co(S(C2B10H10)SC(C6H5)CHCHC(C6H5))] (948025-04-5)

Guidance literature:

In dichloromethane; (Ar); std.Schlenk technique; PhCCH was added to soln. of Co complex in CH2Cl2; mixt. was stirred at ambient temp. for 24 h; solvent removed; chromd. (silica gel, petroleum ether, petroleum ether/CH2Cl2, 10/1); elem. anal.;

DOI:10.1021/om700454p

Reference yield:

(η(5)-C5H5)Co(η(2)-S2C2B10H10) (234756-09-3) + phenylacetylene (536-74-3) → [(η(5)-C5H5)Co]2S2C2B10H10 (234756-10-6) + [(C5H5)Co(S(C2B10H9)SC(C6H5)CH2)] (948025-07-8)

Guidance literature:

In toluene; byproducts: 1,3,5-triphenylbenzene, 1,2,4-triphenylbenzene; (Ar); std.Schlenk technique; PhCCH was added to soln. of Co complex in toluene; mixt. was heated at 80°C for 2 h; solvent removed; chromd. (silica gel);

DOI:10.1021/om700454p

Reference yield:

[(C5H5)Co(S(C2B10H10)SC(C6H5)CHCHC(C6H5))] (948025-04-5) + phenylacetylene (536-74-3) → [(η(5)-C5H5)Co]2S2C2B10H10 (234756-10-6) + [(C5H5)Co(S(C2B10H9)SC(C6H5)CH2)] (948025-07-8)

Guidance literature:

In toluene; byproducts: 1,3,5-triphenylbenzene, 1,2,4-triphenylbenzene; (Ar); std. Schlenk technique; PhCCH was added to soln. of Co complex in toluene; mixt. was heated at 80°C for 3 h; solvent removed;

DOI:10.1021/om700454p

upstream raw materials:

(η(5)-C5H5)Co(η(2)-S2C2B10H10)

phenylacetylene

[(C₅H₅)Co(S(C₂B₁₀H₁₀)SC(C₆H₅)CHCHC(C₆H₅))]