PhBi(μ-N-(t-Bu))2BiPh

Base Information

• Chemical Name: PhBi(μ-N-(t-Bu))2BiPh
• CAS No.: 577975-99-6
• Molecular Formula: C₂₀H₂₈Bi₂N₂
• Molecular Weight: 714.417
• Mol file: 577975-99-6.mol

Synonyms:

Chemical Property of PhBi(μ-N-(t-Bu))2BiPh

Chemical Property:

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Technology Process of PhBi(μ-N-(t-Bu))2BiPh

There total 1 articles about PhBi(μ-N-(t-Bu))2BiPh which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 18.0%

(THF)Bi(Ph)Cl2 + lithium tert-butylamide (37828-54-9) → PhBi(μ-N-(t-Bu))2BiPh (577975-99-6)

Guidance literature:

In diethyl ether; byproducts: LiCl, t-BuNH2; to soln. of Sb deriv. in Et2O added sropwise slurry of Li compound (ratio 1:2) in Et2O at 0°C, allowed to warm to 23°C, kept for 3h; concd. in vac., added hexane, centrifuged, decanted, concd., crystd. on standing for 2 d; elem. anal.;

DOI:10.1139/v03-019

upstream raw materials:

lithium tert-butylamide