(+/-)Deoxyschizandrin

Base Information

• Chemical Name: (+/-)Deoxyschizandrin
• CAS No.: 115495-71-1
• Molecular Formula: C₂₄H₃₂O₆
• Molecular Weight: 416.514
• Mol file: 115495-71-1.mol

Synonyms:

Chemical Property of (+/-)Deoxyschizandrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (+/-)Deoxyschizandrin

There total 1 articles about (+/-)Deoxyschizandrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

5,5'-(2,3-dimethylbutane-1,4-diyl)bis(1,2,3-trimethoxybenzene) (50544-08-6,75597-96-5,107191-91-3,115587-61-6,72730-20-2) → schisandrin A (156769-17-4) + (+/-)Deoxyschizandrin (115495-71-1) + (1α,2β,3β)-6,7,8-trimethoxy-2,3-dimethyl-1-(3,4,5-trimethoxyphenyl)-1,2,3,4-tetrahydronaphthalene (14335-63-8,50394-06-4,72777-68-5,90130-15-7,115587-62-7)

Guidance literature:

With ruthenium(IV) oxide; boron trifluoride diethyl etherate; trifluoroacetic acid; trifluoroacetic anhydride; In dichloromethane; for 8h; Product distribution; Mechanism; Ambient temperature; Ti₂O₃ insted of RuO₂*2H₂O, various conditions;

DOI:10.1016/S0040-4020(01)80826-7

upstream raw materials:

5,5'-(2,3-dimethylbutane-1,4-diyl)bis(1,2,3-trimethoxybenzene)

Refernces

• 1、 Dhal,Landais,Lebrun,Lenain,Robin. "Ruthenium dioxide in fluoro acid medium V. Application to the non phenolic oxidative coupling of diarylbutanes. Conformational studies of cis and trans deoxyschizandrins". . p. 1153 - 1164. Retrieved 2007/10/02.