2,4,6-trinitrobenzyl anion

Base Information

• Chemical Name: 2,4,6-trinitrobenzyl anion
• CAS No.: 34403-92-4
• Molecular Formula: C₇H₄N₃O₆
• Molecular Weight: 226.125
• Mol file: 34403-92-4.mol

Synonyms:

Chemical Property of 2,4,6-trinitrobenzyl anion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,4,6-trinitrobenzyl anion

There total 7 articles about 2,4,6-trinitrobenzyl anion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,4,6-Trinitrotoluene (118-96-7) + potassium tert-butylate (865-47-4) → 2,4,6-trinitrobenzyl anion (34403-92-4) + C11H14N3O7(1-)

Guidance literature:

With 18-crown-6 ether; In tert-butyl alcohol; at 30 ℃; Rate constant; at different crown ether to base ratios;

Reference yield:

2,4,6-Trinitrotoluene (118-96-7) + tetra-n-butylammonium tert-butoxide (75649-83-1) → 2,4,6-trinitrobenzyl anion (34403-92-4) + C11H14N3O7(1-)

Guidance literature:

With 18-crown-6 ether; In tert-butyl alcohol; at 30 ℃; Rate constant; at different crown ether to base ratios;

Reference yield:

2,4,6-Trinitrotoluene (118-96-7) + 1-methyl-2,3,4,6,7,8-hexahydro-1H-pyrimido[1,2-a]pyrimidine (84030-20-6) → 2,4,6-trinitrobenzyl anion (34403-92-4) + 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-enium

Guidance literature:

With 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene picrate; In acetonitrile; at 25 ℃; Kinetics;

DOI:10.1139/cjc-77-5-6-1042

upstream raw materials:

2,4,6-Trinitrotoluene

potassium tert-butylate

nitromethane anion

nitroethane carbanion

Refernces

• 1、 Cox, Jonathan P. L.,Crampton, Michael R.,Wight, Paul. "Comparison of the Intrinsic Reactivities of Carbon and Oxygen Nucleophiles at the 1,3,5-Trinitro-substituted Aromatic Ring". . p. 25 - 30. Retrieved 2007/10/02.
• 2、 Norris, Albert R.. "Kinetic studies of the reactions of 2,4,6-trinitrotoluene and 2,4,6-trinitrotoluene-d3 with ion-paired KOBut and free tert-butoxide ion in tert-butanol". . p. 2178 - 2182. Retrieved 2007/10/02.