2-Anthracenecarboxylic acid, 9,10-dihydro-3,5,8-trimethoxy-1-methyl-9,10-dioxo-, phenylmethyl ester

Base Information

Chemical Name:2-Anthracenecarboxylic acid, 9,10-dihydro-3,5,8-trimethoxy-1-methyl-9,10-dioxo-, phenylmethyl ester
CAS No.:141111-41-3
Molecular Formula:C26H22O7
Molecular Weight:446.456
Hs Code.:

Synonyms:

Suppliers and Price of 2-Anthracenecarboxylic acid, 9,10-dihydro-3,5,8-trimethoxy-1-methyl-9,10-dioxo-, phenylmethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-Anthracenecarboxylic acid, 9,10-dihydro-3,5,8-trimethoxy-1-methyl-9,10-dioxo-, phenylmethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-Anthracenecarboxylic acid, 9,10-dihydro-3,5,8-trimethoxy-1-methyl-9,10-dioxo-, phenylmethyl ester

There total 1 articles about 2-Anthracenecarboxylic acid, 9,10-dihydro-3,5,8-trimethoxy-1-methyl-9,10-dioxo-, phenylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 77-78-1
dimethyl sulfate

: 141111-35-5
3,5,8-Trihydroxy-1-methyl-9,10-dioxo-9,10-dihydro-anthracene-2-carboxylic acid benzyl ester

: 141111-41-3
3,5,8-Trimethoxy-1-methyl-9,10-dioxo-9,10-dihydro-anthracene-2-carboxylic acid benzyl ester

Guidance literature:: With potassium carbonate; In acetone; for 24h; Heating;
DOI:10.1039/a705145j

Reference yield:

: 141111-41-3
3,5,8-Trimethoxy-1-methyl-9,10-dioxo-9,10-dihydro-anthracene-2-carboxylic acid benzyl ester

: 203853-35-4
3,5,8-Trimethoxy-1-methyl-9,10-dioxo-7-((2S,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-9,10-dihydro-anthracene-2-carboxylic acid benzyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) aq. sodium dithionite, Bu₄NBr, KOH / 1.) THF, 15 min; 10 min, 2.) 0 deg C, 2 h; 0 deg C to r.t.

2: BF₃*Et₂O / CH₂Cl₂ / 1.) -40 deg C to r.t., 2.) r.t., 24 h

3: PCC / CH₂Cl₂ / 0.25 h

With potassium hydroxide; sodium dithionite; boron trifluoride diethyl etherate; tetrabutylammomium bromide; pyridinium chlorochromate; In dichloromethane;
DOI:10.1039/a705145j

Reference yield:

: 141111-41-3
3,5,8-Trimethoxy-1-methyl-9,10-dioxo-9,10-dihydro-anthracene-2-carboxylic acid benzyl ester

: 203853-33-2
3,5,8,9,10-Pentamethoxy-1-methyl-7-((2S,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-anthracene-2-carboxylic acid benzyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) aq. sodium dithionite, Bu₄NBr, KOH / 1.) THF, 15 min; 10 min, 2.) 0 deg C, 2 h; 0 deg C to r.t.

2: BF₃*Et₂O / CH₂Cl₂ / 1.) -40 deg C to r.t., 2.) r.t., 24 h

With potassium hydroxide; sodium dithionite; boron trifluoride diethyl etherate; tetrabutylammomium bromide; In dichloromethane;
DOI:10.1039/a705145j