rel-(2R,3R)-2-Methyl-1-(1R,2S,4R)-7-oxabicyclo[2.2.1]hept-5-en-2-yl-3-phenyl-3-[(trimethylsilyl)oxy]-1-propanone

Base Information

Chemical Name:rel-(2R,3R)-2-Methyl-1-(1R,2S,4R)-7-oxabicyclo[2.2.1]hept-5-en-2-yl-3-phenyl-3-[(trimethylsilyl)oxy]-1-propanone
CAS No.:119031-08-2
Molecular Formula:C₁₉H₂₆O₃Si
Molecular Weight:330.499
Hs Code.:
DSSTox Substance ID:DTXSID701107765

Synonyms:DTXSID701107765;119031-08-2;rel-(2R,3R)-2-Methyl-1-(1R,2S,4R)-7-oxabicyclo[2.2.1]hept-5-en-2-yl-3-phenyl-3-[(trimethylsilyl)oxy]-1-propanone

Suppliers and Price of rel-(2R,3R)-2-Methyl-1-(1R,2S,4R)-7-oxabicyclo[2.2.1]hept-5-en-2-yl-3-phenyl-3-[(trimethylsilyl)oxy]-1-propanone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of rel-(2R,3R)-2-Methyl-1-(1R,2S,4R)-7-oxabicyclo[2.2.1]hept-5-en-2-yl-3-phenyl-3-[(trimethylsilyl)oxy]-1-propanone

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:6
Exact Mass:330.16512122
Heavy Atom Count:23
Complexity:462

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C(C1=CC=CC=C1)O[Si](C)(C)C)C(=O)C2CC3C=CC2O3
Isomeric SMILES:C[C@H]([C@H](C1=CC=CC=C1)O[Si](C)(C)C)C(=O)[C@H]2C[C@@H]3C=C[C@H]2O3

Technology Process of rel-(2R,3R)-2-Methyl-1-(1R,2S,4R)-7-oxabicyclo[2.2.1]hept-5-en-2-yl-3-phenyl-3-[(trimethylsilyl)oxy]-1-propanone

There total 2 articles about rel-(2R,3R)-2-Methyl-1-(1R,2S,4R)-7-oxabicyclo[2.2.1]hept-5-en-2-yl-3-phenyl-3-[(trimethylsilyl)oxy]-1-propanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 59274-95-2,94224-55-2,94224-56-3,119030-97-6,119030-98-7
(1S,2R,4S)-7-Oxa-bicyclo[2.2.1]hept-5-ene-2-carbaldehyde

: 119031-08-2,119069-83-9,119069-84-0,119069-85-1
oxa-7 exo (syn 2,3 methyl-2 phenyl-3 trimethylsiloxy-3 propanone-1 yl-1)-5 bicyclo<2.2.1>heptene-2

Guidance literature:: Multi-step reaction with 3 steps

1: diethyl ether

2: Swern oxidation

In diethyl ether;
DOI:10.1016/S0040-4020(01)81704-X