4-benzyloxy-3,8c-bis(trifluoromethyl)-1,1a,2,8c-tetrahydro-3H-1,2,8b-epoxymethenocyclopropafluorene

Base Information

• Chemical Name: 4-benzyloxy-3,8c-bis(trifluoromethyl)-1,1a,2,8c-tetrahydro-3H-1,2,8b-epoxymethenocyclopropafluorene
• CAS No.: 127239-66-1
• Molecular Formula: C₂₄H₁₄F₆O₃
• Molecular Weight: 464.364
• Mol file: 127239-66-1.mol

Synonyms:

Chemical Property of 4-benzyloxy-3,8c-bis(trifluoromethyl)-1,1a,2,8c-tetrahydro-3H-1,2,8b-epoxymethenocyclopropafluorene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-benzyloxy-3,8c-bis(trifluoromethyl)-1,1a,2,8c-tetrahydro-3H-1,2,8b-epoxymethenocyclopropafluorene

There total 1 articles about 4-benzyloxy-3,8c-bis(trifluoromethyl)-1,1a,2,8c-tetrahydro-3H-1,2,8b-epoxymethenocyclopropafluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

furan (110-00-9) + <α,α-bis(3,3,3-trifluoropropynyl)>benzyl benzoate (127263-10-9) → (Z)-5-(α-benzoyloxybenzylidene)-1,4-bis(trifluoromethyl)-8-oxatricyclo<4.3.0.02,9>non-3,6-diene (145028-37-1) + 8,9-dibenzoyl-4,7-bis(trifluoromethyl)-2-oxatetracyclo<4.3.0.03,5.04,9>non-7-ene (127239-65-0) + 4-benzyloxy-3,8c-bis(trifluoromethyl)-1,1a,2,8c-tetrahydro-3H-1,2,8b-epoxymethenocyclopropafluorene (127239-66-1) + 4-benzoyloxy-3,8c-bis(trifluoromethyl)-1,1a,2,8c-tetrahydro-4H-1,2,8b-epoxymethenocyclopropafluorene (127239-63-8)

Guidance literature:

In dichloromethane; at 50 ℃; for 144h; Mechanism; Product distribution; or 1,1-bis(3,3,3-trifluoropropynyl)ethyl ethanoate; or reaction with cyclopentadiene;

upstream raw materials:

furan

<α,α-bis(3,3,3-trifluoropropynyl)>benzyl benzoate