acetonitrile(1-diphenylarsino-2-diphenylphosphinoethane)(η5-cyclopentadienyl)ruthenium hexafluorophosphate

Base Information

• Chemical Name: acetonitrile(1-diphenylarsino-2-diphenylphosphinoethane)(η5-cyclopentadienyl)ruthenium hexafluorophosphate
• CAS No.: 708277-40-1
• Molecular Formula: C₃₃H₃₂AsNPRu*F₆P
• Molecular Weight: 794.553

Synonyms:

Chemical Property of acetonitrile(1-diphenylarsino-2-diphenylphosphinoethane)(η5-cyclopentadienyl)ruthenium hexafluorophosphate

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Technology Process of acetonitrile(1-diphenylarsino-2-diphenylphosphinoethane)(η5-cyclopentadienyl)ruthenium hexafluorophosphate

There total 3 articles about acetonitrile(1-diphenylarsino-2-diphenylphosphinoethane)(η5-cyclopentadienyl)ruthenium hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate + 1-diphenylarsino-2-diphenylphosphinoethane (23582-06-1) → acetonitrile(1-diphenylarsino-2-diphenylphosphinoethane)(η5-cyclopentadienyl)ruthenium hexafluorophosphate (708277-40-1) + [((η5-cyclopentadienyl)Ru(acetonitrile)2)2(μ-1-diphenylarsino-2-diphenylphosphinoethane)](PF6)2 + [((η5-cyclopentadienyl)Ru(acetonitrile)2)(μ-1-diphenylarsino-2-diphenylphosphinoethane)2](PF6)2 + [((η5-cyclopentadienyl)Ru(acetonitrile)2)(μ-1-diphenylarsino-2-diphenylphosphinoethane)2](PF6)2

Guidance literature:

In dichloromethane; under Ar; soln. of ligand (1 equiv.) in CH2Cl2 added at room temp. to Rucomplex in CH2Cl2; left at room temp. overnight; filtered; ppt. washed (Et2O), dried; solvent of filtrate removed in vac., washed (Et2O), extd. with cold THF, extract concd., Et2O added, ppt. washed with petroleum ether, dried under vac.; solid after THF extractiondried; elem. anal.;

DOI:10.1016/j.jorganchem.2004.02.035

Reference yield:

[((η5-cyclopentadienyl)Ru(acetonitrile)2)(μ-1-diphenylarsino-2-diphenylphosphinoethane)2](PF6)2 → acetonitrile(1-diphenylarsino-2-diphenylphosphinoethane)(η5-cyclopentadienyl)ruthenium hexafluorophosphate (708277-40-1)

Guidance literature:

In dichloromethane; under Ar; Ru complex in CH2Cl2 warmed for 24 h;

DOI:10.1016/j.jorganchem.2004.02.035

Reference yield:

[((η5-cyclopentadienyl)Ru(acetonitrile)2)(μ-1-diphenylarsino-2-diphenylphosphinoethane)2](PF6)2 → acetonitrile(1-diphenylarsino-2-diphenylphosphinoethane)(η5-cyclopentadienyl)ruthenium hexafluorophosphate (708277-40-1)

Guidance literature:

In dichloromethane; under Ar; Ru complex in CH2Cl2 warmed for 24 h;

DOI:10.1016/j.jorganchem.2004.02.035

upstream raw materials:

1-diphenylarsino-2-diphenylphosphinoethane

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