(Z)-diethyl acetamido<2-(phenylsulfonyl)vinyl>malonate

Base Information

• Chemical Name: (Z)-diethyl acetamido<2-(phenylsulfonyl)vinyl>malonate
• CAS No.: 103384-11-8
• Molecular Formula: C₁₇H₂₁NO₇S
• Molecular Weight: 383.422
• Mol file: 103384-11-8.mol

Synonyms:

Chemical Property of (Z)-diethyl acetamido<2-(phenylsulfonyl)vinyl>malonate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (Z)-diethyl acetamido<2-(phenylsulfonyl)vinyl>malonate

There total 1 articles about (Z)-diethyl acetamido<2-(phenylsulfonyl)vinyl>malonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(Phenylsulfonyl)-2-(trimethylsilyl)acetylene (32501-93-2) + 2-acetylaminomalonic acid diethyl ester (1068-90-2) → (Z)-diethyl acetamido<2-(phenylsulfonyl)vinyl>malonate (103384-11-8) + (E)-diethyl acetamido<2-(phenylsulfonyl)vinyl>malonate (103384-10-7)

Guidance literature:

With potassium tert-butylate; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, RT, 1 h, 2.) THF, from -15 deg C to -10 deg C, 1 h;

DOI:10.1021/jo00367a031

upstream raw materials:

1-(Phenylsulfonyl)-2-(trimethylsilyl)acetylene

2-acetylaminomalonic acid diethyl ester