{exo-9-(Cl-trans-(PPh₃)2-cis-H₂Ir)-arachno-6-SB₉H₁₁}

Base Information

• Chemical Name: {exo-9-(Cl-trans-(PPh₃)2-cis-H₂Ir)-arachno-6-SB₉H₁₁}
• CAS No.: 139108-02-4
• Molecular Formula: C₃₆H₄₃B₉ClIrP₂S
• Molecular Weight: 894.723
• Mol file: 139108-02-4.mol

Synonyms:

Chemical Property of {exo-9-(Cl-trans-(PPh₃)2-cis-H₂Ir)-arachno-6-SB₉H₁₁}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {exo-9-(Cl-trans-(PPh₃)2-cis-H₂Ir)-arachno-6-SB₉H₁₁}

There total 1 articles about {exo-9-(Cl-trans-(PPh₃)2-cis-H₂Ir)-arachno-6-SB₉H₁₁} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 9.9%

bis(triphenylphosphine)carbonyliridium(I) chloride (59246-46-7,14871-41-1,15318-31-7) + cesium(1+)*arachno-6-SB9H12(1-) → {exo-9-(Cl-trans-(PPh3)2-cis-H2Ir)-arachno-6-SB9H11} (139108-02-4)

Guidance literature:

In chloroform; stirring (N2-atmosphere, 12 days); filtration, partial evapn. (room temp., reduced pressure), repeated chromy. (thin-layer on SiO2 and high-pressure liquid on Lichrosorb, CH2Cl2/hexane 2:3);

DOI:10.1039/DT9910002657

Reference yield:

{exo-9-(Cl-trans-(PPh3)2-cis-H2Ir)-arachno-6-SB9H11} (139108-02-4) → 9-(PPh3)-arachno-6-SB9H11 (139108-03-5)

Guidance literature:

In ⁽²⁾H₈-toluene; 100°C, 30 min.; not isolated, detected by (31)P-NMR spectroscopy (80% yield);

DOI:10.1039/DT9910002657

upstream raw materials:

bis(triphenylphosphine)carbonyliridium(I) chloride

Downstream raw materials:

9-(PPh₃)-arachno-6-SB₉H₁₁