dilithium cis-dimethyldiphenylpalladate(II)

Base Information

Chemical Name:dilithium cis-dimethyldiphenylpalladate(II)
CAS No.:83997-79-9
Molecular Formula:C₁₄H₁₆Pd*2Li
Molecular Weight:304.583
Hs Code.:

Synonyms:

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Chemical Property of dilithium cis-dimethyldiphenylpalladate(II)

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Technology Process of dilithium cis-dimethyldiphenylpalladate(II)

There total 2 articles about dilithium cis-dimethyldiphenylpalladate(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 77881-04-0
cis-PdMe₂(PEt₂Ph)2

: 591-51-5
phenyllithium

: 83997-79-9
dilithium cis-dimethyldiphenylpalladate(II)

Guidance literature:: In tetrahydrofuran; byproducts: diethyl(phenyl)phosphine; 1 equiv of PhLi was added at -75°C under inert atmosphere to a soln. of Pd-complex in THF, reaction was monitored by (1)H NMR spectroscopy at room temp. for a few days; not isolated; (1)H NMR spectral data;
DOI:10.1021/om00074a007

Reference yield:

: 77831-30-2
trans-PdMe₂(PEt₂Ph)2

: 591-51-5
phenyllithium

: 83997-79-9
dilithium cis-dimethyldiphenylpalladate(II)

: 83947-31-3
dilithium trans-dimethyldiphenylpalladate(II)

: cis-{PdMe₂Ph(PEt₂Ph)}Li

Guidance literature:: In tetrahydrofuran; byproducts: diethyl(phenyl)phosphine; PhLi (1 equiv) was added at -75°C under inert atmosphere to Pd-complex in THF, reaction was monitored by (1)H NMR spectra at room temp. for several hours; only trans-Li(PdPhMe2(PEt2Ph)) and trans-Li2(PdPh2Me2) were observed after a few minutes; not isolated; (1)H NMR spectral data;
DOI:10.1021/om00074a007