tetra-μ-2-fluorobenzoato-κ10O:O';O:O,O';O:O';O,O':O'-bis[aqua(4,4'-bipyridine-κN)(2-fluorobenzoato-κO)lanthanum(III)]

Base Information

• Chemical Name: tetra-μ-2-fluorobenzoato-κ10O:O';O:O,O';O:O';O,O':O'-bis[aqua(4,4'-bipyridine-κN)(2-fluorobenzoato-κO)lanthanum(III)]
• CAS No.: 709030-87-5
• Molecular Formula: C₆₂H₄₄F₆La₂N₄O₁₄
• Molecular Weight: 1460.85
• Mol file: 709030-87-5.mol

Synonyms:

Chemical Property of tetra-μ-2-fluorobenzoato-κ10O:O';O:O,O';O:O';O,O':O'-bis[aqua(4,4'-bipyridine-κN)(2-fluorobenzoato-κO)lanthanum(III)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetra-μ-2-fluorobenzoato-κ10O:O';O:O,O';O:O';O,O':O'-bis[aqua(4,4'-bipyridine-κN)(2-fluorobenzoato-κO)lanthanum(III)]

There total 1 articles about tetra-μ-2-fluorobenzoato-κ10O:O';O:O,O';O:O';O,O':O'-bis[aqua(4,4'-bipyridine-κN)(2-fluorobenzoato-κO)lanthanum(III)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4,4'-bipyridine (553-26-4) + lanthanum(III) chloride hexahydrate (10025-84-0,20211-76-1) + o-fluoro-benzoic acid (445-29-4) → tetra-μ-2-fluorobenzoato-κ10O:O';O:O,O';O:O';O,O':O'-bis[aqua(4,4'-bipyridine-κN)(2-fluorobenzoato-κO)lanthanum(III)] (709030-87-5)

Guidance literature:

With NaOH; In ethanol; water; soln. of 2-fluorobenzoic acid (0.5 mol) (EtOH) adjusted to pH 6-7 with aq. soln. of NaOH; soln. of 4,4'-bipyridine (0.5 mol) and LaCl3*6H2O (0.5mol) (EtOH) added; mixt. heated under reflux with stirring for 2 h; ppt. filtered off; crystd. after one month at room temp.;

DOI:10.1107/S0108270103029470

upstream raw materials:

4,4'-bipyridine

lanthanum(III) chloride hexahydrate

o-fluoro-benzoic acid

Refernces