Zr[tert-BuN(CH₂CH₂C(O)Ph₂)2][CH₂Ph]2

Base Information

• Chemical Name: Zr[tert-BuN(CH₂CH₂C(O)Ph₂)2][CH₂Ph]2
• CAS No.: 260370-16-9
• Molecular Formula: C₄₈H₅₁NO₂Zr
• Molecular Weight: 765.162
• Mol file: 260370-16-9.mol

Synonyms:

Chemical Property of Zr[tert-BuN(CH₂CH₂C(O)Ph₂)2][CH₂Ph]2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Zr[tert-BuN(CH₂CH₂C(O)Ph₂)2][CH₂Ph]2

There total 2 articles about Zr[tert-BuN(CH₂CH₂C(O)Ph₂)2][CH₂Ph]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrabenzylzirconium(IV) (24356-01-2) + 3-[tert-butyl-(3-hydroxy-3,3-diphenyl-propyl)-amino]-1,1-diphenyl-propan-1-ol (260370-09-0) → Zr[tert-BuN(CH2CH2C(O)Ph2)2][CH2Ph]2 (260370-16-9)

Guidance literature:

In toluene; under Ar atm. soln. HOCPh2CH2CH2N(t-Bu)CH2CH2CPh2OH in toluene was added dropwise at -78°C to soln. tetrabenzylzirconium in toluene, mixt. was stirred for 30 min; solvent was removed in vacuo, residue was recrystd. from toluene-hexane; elem. anal.;

DOI:10.1021/om9907324

Reference yield:

Zr[tert-BuN(CH2CH2C(O)Ph2)2]2 + tetrabenzylzirconium(IV) (24356-01-2) → Zr[tert-BuN(CH2CH2C(O)Ph2)2][CH2Ph]2 (260370-16-9)

Guidance literature:

In toluene; under Ar atm. tetrbenzylzirconium was reacted with bis(ligand) complex in toluene for 30 min; product was recrystd. from toluene-hexane; elem. anal.;

DOI:10.1021/om9907324

upstream raw materials:

tetrabenzylzirconium(IV)

3-[tert-butyl-(3-hydroxy-3,3-diphenyl-propyl)-amino]-1,1-diphenyl-propan-1-ol