NiBr((CH₂CHCH₂CH₂)2As(CH₂CH₂CH₂As(CH₃)2))2⁽¹⁺⁾*B(C₆H₅)4^(1-)=NiBr((CH₂CHCH₂CH₂)2As(CH₂CH₂CH₂As(CH₃)2))2B(C₆H₅)4

Base Information

• Chemical Name: NiBr((CH₂CHCH₂CH₂)2As(CH₂CH₂CH₂As(CH₃)2))2⁽¹⁺⁾*B(C₆H₅)4^(1-)=NiBr((CH₂CHCH₂CH₂)2As(CH₂CH₂CH₂As(CH₃)2))2B(C₆H₅)4
• CAS No.: 100562-93-4
• Molecular Formula: C₂₄H₂₀B*C₂₆H₅₂As₄BrNi
• Molecular Weight: 1122.21
• Mol file: 100562-93-4.mol

Synonyms:

Chemical Property of NiBr((CH₂CHCH₂CH₂)2As(CH₂CH₂CH₂As(CH₃)2))2⁽¹⁺⁾*B(C₆H₅)4^(1-)=NiBr((CH₂CHCH₂CH₂)2As(CH₂CH₂CH₂As(CH₃)2))2B(C₆H₅)4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of NiBr((CH₂CHCH₂CH₂)2As(CH₂CH₂CH₂As(CH₃)2))2⁽¹⁺⁾*B(C₆H₅)4^(1-)=NiBr((CH₂CHCH₂CH₂)2As(CH₂CH₂CH₂As(CH₃)2))2B(C₆H₅)4

There total 2 articles about NiBr((CH₂CHCH₂CH₂)2As(CH₂CH₂CH₂As(CH₃)2))2⁽¹⁺⁾*B(C₆H₅)4^(1-)=NiBr((CH₂CHCH₂CH₂)2As(CH₂CH₂CH₂As(CH₃)2))2B(C₆H₅)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-dimethylarsinopropylbis(but-3-enyl)arsine (100641-23-4) → NiBr((CH2CHCH2CH2)2As(CH2CH2CH2As(CH3)2))2(1+)*B(C6H5)4(1-)=NiBr((CH2CHCH2CH2)2As(CH2CH2CH2As(CH3)2))2B(C6H5)4 (100562-93-4)

Guidance literature:

Multi-step reaction with 2 steps

1: ethanol

2: ethanol

In ethanol;

DOI:10.1016/0022-328X(85)80069-3

Reference yield:

NiBr((CH2CHCH2CH2)2As(CH2CH2CH2As(CH3)2))2(1+)*Br(1-)=NiBr((CH2CHCH2CH2)2As(CH2CH2CH2As(CH3)2))2Br (100562-91-2) + sodium tetraphenyl borate (143-66-8) → NiBr((CH2CHCH2CH2)2As(CH2CH2CH2As(CH3)2))2(1+)*B(C6H5)4(1-)=NiBr((CH2CHCH2CH2)2As(CH2CH2CH2As(CH3)2))2B(C6H5)4 (100562-93-4)

Guidance literature:

In ethanol; NaBPh4 was added to an ethanolic soln. of Ni-complex in 1:1 molar ratio; evapd., residue extd. with CH2Cl2, ext. filtered under N2, evapd. (N2),BuOH was added, mixt. stirred at -70°C, solid was rapidly collected on a pre-cooled filter stick under N2 and transferred to a number ofsmall sample tubes; elem. anal.;

DOI:10.1016/0022-328X(85)80069-3

upstream raw materials:

NiBr((CH₂CHCH₂CH₂)2As(CH₂CH₂CH₂As(CH₃)2))2⁽¹⁺⁾*Br^(1-)=NiBr((CH₂CHCH₂CH₂)2As(CH₂CH₂CH₂As(CH₃)2))2Br

sodium tetraphenyl borate

3-dimethylarsinopropylbis(but-3-enyl)arsine