((4-trimethylsilyloxyphenyl)pyridine-2-ylmethyleneamine)Mo(CO)3((4-isocyanophenyl)pyridine-2-ylmethyleneamine)Mo(CO)4

Base Information

• Chemical Name: ((4-trimethylsilyloxyphenyl)pyridine-2-ylmethyleneamine)Mo(CO)3((4-isocyanophenyl)pyridine-2-ylmethyleneamine)Mo(CO)4
• CAS No.: 702645-49-6
• Molecular Formula: C₃₅H₂₇Mo₂N₅O₈Si
• Molecular Weight: 865.594
• Mol file: 702645-49-6.mol

Synonyms:

Chemical Property of ((4-trimethylsilyloxyphenyl)pyridine-2-ylmethyleneamine)Mo(CO)3((4-isocyanophenyl)pyridine-2-ylmethyleneamine)Mo(CO)4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ((4-trimethylsilyloxyphenyl)pyridine-2-ylmethyleneamine)Mo(CO)3((4-isocyanophenyl)pyridine-2-ylmethyleneamine)Mo(CO)4

There total 1 articles about ((4-trimethylsilyloxyphenyl)pyridine-2-ylmethyleneamine)Mo(CO)3((4-isocyanophenyl)pyridine-2-ylmethyleneamine)Mo(CO)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

tris(acetonitrile)tricarbonylmolybdenum(0) (15038-48-9,17731-95-2) + [Mo(CO)4(NCCH3)2] (14126-87-5,17594-19-3) + (4-isocyanophenyl)pyridine-2-yl-methyleneamine (628728-88-1) + pyridine-2-ylmethylene-(4-trimethylsilanyloxyphenyl)amine (362013-18-1) → ((4-trimethylsilyloxyphenyl)pyridine-2-ylmethyleneamine)Mo(CO)3((4-isocyanophenyl)pyridine-2-ylmethyleneamine)Mo(CO)4 (702645-49-6)

Guidance literature:

In tetrahydrofuran; all manipulations under Ar atm.; ((MeCN)3Mo(CO)3) treated with Si compd.in THF, stirred for 15 min, solid CN-compd. added, after 10 min soln. o f ((MeCN)2Mo(CO)4) added, stirred for 30 min; celite added, evapd. to dryness, chromy. (silica gel, Et2O then THF, at 0°C), THF fraction concd., layered with petroleum ether, ppt. collected, dried in vac., elem. anal.; intermediates controlled by IR;

DOI:10.1002/ejic.200300272

upstream raw materials:

tris(acetonitrile)tricarbonylmolybdenum⁽⁰⁾

[Mo(CO)₄(NCCH₃)₂]

(4-isocyanophenyl)pyridine-2-yl-methyleneamine

pyridine-2-ylmethylene-(4-trimethylsilanyloxyphenyl)amine