(P(C(CH₃)3)2C₅H₉P(C(CH₃)3)2)NiNCCHCH₂⁽¹⁺⁾*B(C₆H₅)4^(1-)=(P(C₄H₉)2C₅H₉P(C₄H₉)2)Ni(NCCHCH₂)B(C₆H₅)4

Base Information

• Chemical Name: (P(C(CH₃)3)2C₅H₉P(C(CH₃)3)2)NiNCCHCH₂⁽¹⁺⁾*B(C₆H₅)4^(1-)=(P(C₄H₉)2C₅H₉P(C₄H₉)2)Ni(NCCHCH₂)B(C₆H₅)4
• CAS No.: 876274-30-5
• Molecular Formula: C₂₄H₂₀B*C₂₄H₄₈NNiP₂
• Molecular Weight: 790.523
• Mol file: 876274-30-5.mol

Synonyms:

Chemical Property of (P(C(CH₃)3)2C₅H₉P(C(CH₃)3)2)NiNCCHCH₂⁽¹⁺⁾*B(C₆H₅)4^(1-)=(P(C₄H₉)2C₅H₉P(C₄H₉)2)Ni(NCCHCH₂)B(C₆H₅)4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (P(C(CH₃)3)2C₅H₉P(C(CH₃)3)2)NiNCCHCH₂⁽¹⁺⁾*B(C₆H₅)4^(1-)=(P(C₄H₉)2C₅H₉P(C₄H₉)2)Ni(NCCHCH₂)B(C₆H₅)4

There total 1 articles about (P(C(CH₃)3)2C₅H₉P(C(CH₃)3)2)NiNCCHCH₂⁽¹⁺⁾*B(C₆H₅)4^(1-)=(P(C₄H₉)2C₅H₉P(C₄H₉)2)Ni(NCCHCH₂)B(C₆H₅)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(P(C(CH3)3)2C5H9P(C(CH3)3)2)NiNCCHCH2(1+)*B(C6H5)4(1-)*H2O=(P(C4H9)2C5H9P(C4H9)2)Ni(NCCHCH2)B(C6H5)4*H2O + acetonitrile (75-05-8,26809-02-9) → (P(C(CH3)3)2C5H9P(C(CH3)3)2)NiNCCHCH2(1+)*B(C6H5)4(1-)=(P(C4H9)2C5H9P(C4H9)2)Ni(NCCHCH2)B(C6H5)4 (876274-30-5)

Guidance literature:

In chloroform-d1; acetonitrile was added to an NMR sample containing a soln. of complex inCDCl3; not sepd., detected by NMR spectra; Kinetics;

DOI:10.1021/om050844x

Reference yield:

(P(C(CH3)3)2C5H9P(C(CH3)3)2)NiNCCHCH2(1+)*B(C6H5)4(1-)=(P(C4H9)2C5H9P(C4H9)2)Ni(NCCHCH2)B(C6H5)4 (876274-30-5) + acrylonitrile (107-13-1,25014-41-9) → (P(C(CH3)3)2C5H9P(C(CH3)3)2)NiNCCHCH2(1+)*B(C6H5)4(1-)*H2O=(P(C4H9)2C5H9P(C4H9)2)Ni(NCCHCH2)B(C6H5)4*H2O

Guidance literature:

In chloroform-d1; acrylonitrile was added to an NMR sample containing a soln. of complex in CDCl3; not sepd., detected by NMR spectra; Kinetics;

DOI:10.1021/om050844x

Reference yield:

[(HC(C2H4P(C(CH3)3)2)2)Ni(NCCHCH2)](1+)*B(C6H5)4(1-)=[(HC(C2H4P(C(CH3)3)2)2)Ni(NCCHCH2)]B(C6H5)4 (876274-30-5) + aniline (62-53-3) → [(HC(C2H4P(C(CH3)3)2)2)Ni(NCC2H4NHC6H5)](1+)*B(C6H5)4(1-)*H2O=[(HC(C2H4P(C(CH3)3)2)2)Ni(NCC2H4NHC6H5)]B(C6H5)4*H2O

Guidance literature:

In benzene-d6; (N2); std. Schlenk technique; aniline was added to soln. of Ni complex in C6D6; heated at 80°C for 16 h; NMR monitoring;

DOI:10.1021/om800840u

upstream raw materials:

acetonitrile