[(p-cymene)RuCl(η(2)-(S)-BINAP monoxide-P,O)]Cl

Base Information

• Chemical Name: [(p-cymene)RuCl(η(2)-(S)-BINAP monoxide-P,O)]Cl
• CAS No.: 268545-59-1
• Molecular Formula: C₅₄H₄₆ClOP₂Ru*Cl
• Molecular Weight: 944.882
• Mol file: 268545-59-1.mol

Synonyms:

Chemical Property of [(p-cymene)RuCl(η(2)-(S)-BINAP monoxide-P,O)]Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(p-cymene)RuCl(η(2)-(S)-BINAP monoxide-P,O)]Cl

There total 2 articles about [(p-cymene)RuCl(η(2)-(S)-BINAP monoxide-P,O)]Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + (R)-2-(diphenylphosphino)-2'-(diphenylphosphinyl)-1,1'-binaphthyl (183244-55-5,152646-80-5,204862-91-9) → [(p-cymene)RuCl(η(2)-(R)-BINAP monoxide-P,O)]Cl (268545-59-1,267899-87-6)

Guidance literature:

In dichloromethane; stoich. amt. of (R)-bisphosphine monoxide ligand was added to a CH2Cl2 soln. of (p-cymeneRuCl2)2 under N2, 48 h; solvent was removed, residue was recrystd. from mixt. of CH2Cl2 and Et2O under N2, elem. anal.;

DOI:10.1021/om000014d

Reference yield:

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + (S)-2-(diphenylphosphino)-2'-(diphenylphosphinyl)-1,1'-binaphthyl (183244-55-5,204862-91-9,152646-80-5) → [(p-cymene)RuCl(η(2)-(S)-BINAP monoxide-P,O)]Cl (267899-87-6,268545-59-1)

Guidance literature:

In dichloromethane;

DOI:10.1021/om000014d

upstream raw materials:

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

(R)-2-(diphenylphosphino)-2'-(diphenylphosphinyl)-1,1'-binaphthyl

(S)-2-(diphenylphosphino)-2'-(diphenylphosphinyl)-1,1'-binaphthyl