trans,trans,trans-[Ru(NC₅H₄NNC₆H₄-p-Cl)2Cl₂]

Base Information

• Chemical Name: trans,trans,trans-[Ru(NC₅H₄NNC₆H₄-p-Cl)2Cl₂]
• CAS No.: 648928-41-0
• Molecular Formula: C₂₂H₁₆Cl₄N₆Ru
• Molecular Weight: 607.291
• Mol file: 648928-41-0.mol

Synonyms:

Chemical Property of trans,trans,trans-[Ru(NC₅H₄NNC₆H₄-p-Cl)2Cl₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans,trans,trans-[Ru(NC₅H₄NNC₆H₄-p-Cl)2Cl₂]

There total 1 articles about trans,trans,trans-[Ru(NC₅H₄NNC₆H₄-p-Cl)2Cl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(4-chlorophenylazo)pyridine (14458-12-9) + (2,2':6',2''-terpyridine)trichlororuthenium(III) (72905-30-7) + sodium perchlorate → trans,trans,trans-[Ru(NC5H4NNC6H4-p-Cl)2Cl2] (186262-96-4,325148-47-8,648928-41-0) + cis-trans-cis-dichlorobis(2-(4'-chlorophenylazo)pyridine)ruthenium(II) + chloro(2,2':6,2''-terpyridine)(NC5H4NNC6H4-p-Cl)ruthenium(II) perchlorate (324765-53-9)

Guidance literature:

With triethyl amine; LiCl; In ethanol; water; soln. of Ru complex in EtOH-water heated at reflux for 5 min; 1 equiv. of ligand followed by LiCl and NEt3 added to hot soln.; heated to refluxfor 5 h; solvent removed under reduced pressure; dissolved in MeCN; satd. aq. soln. of NaClO4 added; kept in refrigerator overnight; filtered; ppt. washed with ice-cold water; dried in vac. over P4O10; purified by column chromy. (silica gel, CH2Cl2-MeCN); red band collected; solvent evapd. under reduced pressure; characterized by elem. anal.;

DOI:10.1039/b005789o

upstream raw materials:

2-(4-chlorophenylazo)pyridine

(2,2':6',2''-terpyridine)trichlororuthenium(III)