Ir(CO)(NS)Cl₂(P(C₆H₅)3)2

Base Information

• Chemical Name: Ir(CO)(NS)Cl₂(P(C₆H₅)3)2
• CAS No.: 80432-26-4
• Molecular Formula: C₃₇H₃₀Cl₂IrNOP₂S
• Molecular Weight: 861.791
• Mol file: 80432-26-4.mol

Synonyms:

Chemical Property of Ir(CO)(NS)Cl₂(P(C₆H₅)3)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ir(CO)(NS)Cl₂(P(C₆H₅)3)2

There total 2 articles about Ir(CO)(NS)Cl₂(P(C₆H₅)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

bis(triphenylphosphine)iridium(I) carbonyl chloride (15318-31-7,14871-41-1,59246-46-7) + trithiazyl chloride (105453-99-4,105454-00-0,5964-00-1) → Ir(CO)(NS)Cl2(P(C6H5)3)2 (80432-26-4)

Guidance literature:

In tetrahydrofuran; Ar atmosphere; addn. of a soln. of (NSCl)3 in THF to a stirred soln. ofVaska's complex in THF; after complete addn. the soln. was stirred for 1 h;; removal of solvent under reduced pressure; extn. with benzene; pptn. byaddn. of petroleum ether to the extract; the ppt. was sepd., washed with petroleum ether and H2O several times, dried in air, and recrystd. from C6H6/petroleum ether; elem. anal.;;

Reference yield:

IrH(CO)(P(C6H5)3)2 (39708-98-0,19154-27-9,16923-63-0) + (x)C4H8O*ClNS → Ir(CO)(NS)Cl2(P(C6H5)3)2 (80432-26-4)

Guidance literature:

In not given; elem. anal.;;

upstream raw materials:

IrH(CO)(P(C₆H₅)3)2

bis(triphenylphosphine)iridium(I) carbonyl chloride

trithiazyl chloride