[Mo(phenyl isocyanate)Cl₃(2,4-di-tert-butyl-6-((dimethylamino)methyl)phenolate)]

Base Information

• Chemical Name: [Mo(phenyl isocyanate)Cl₃(2,4-di-tert-butyl-6-((dimethylamino)methyl)phenolate)]
• CAS No.: 1024617-08-0
• Molecular Formula: C₂₃H₃₃Cl₃MoN₂O
• Molecular Weight: 555.827
• Mol file: 1024617-08-0.mol

Synonyms:

Chemical Property of [Mo(phenyl isocyanate)Cl₃(2,4-di-tert-butyl-6-((dimethylamino)methyl)phenolate)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Mo(phenyl isocyanate)Cl₃(2,4-di-tert-butyl-6-((dimethylamino)methyl)phenolate)]

There total 1 articles about [Mo(phenyl isocyanate)Cl₃(2,4-di-tert-butyl-6-((dimethylamino)methyl)phenolate)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

thionyl chloride (7719-09-7) + phenyl isocyanate (1197040-29-1,931-54-4) + 2,4-di-tert-butyl-6-(1,1-dimethylaminomethyl)phenol (32857-07-1) + molybdenum(VI) oxide → [Mo(phenyl isocyanate)Cl3(2,4-di-tert-butyl-6-((dimethylamino)methyl)phenolate)] (1024617-08-0)

Guidance literature:

In dichloromethane; (N2); reflux of MoO3 with SOCl2 for 5 h; removal of volatiles in vac., suspending in CH2Cl2; treatment with 1 equiv. of HOC6H2(t-Bu)2CH2NMe2; reflux for 3h; evapn. of solvent in vac., washing with hexane; dissolving in MePh; addn. of PhNC; reflux for 2h; monitoring by TLC; cooling to room temp.; filtration through short pad of silica; elem. anal.;

DOI:10.1016/j.jorganchem.2008.01.007

upstream raw materials:

thionyl chloride

phenyl isocyanate

2,4-di-tert-butyl-6-(1,1-dimethylaminomethyl)phenol

Refernces