Technology Process of zirconocene bis(2,4,6-trimethylphenyl)arsenide chloride
There total 1 articles about zirconocene bis(2,4,6-trimethylphenyl)arsenide chloride which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
methyllithium;
In
diethyl ether;
byproducts: LiCl; under N2; Et2O soln. of As compd. cooled to -30°C; MeLi added slowly; warmed to ambient temp.; stirred for 1 h; cooled to -30°C; added dropwise to cold (-30°C) suspn. of Zr complex (1 equiv.) in Et2O; stirred (ambient temp., 1 h); soln. filtered through Celite; solvent removed under reduced pressure until solid appeared; warmed to ambient temp. to dissolve the solid; filtered; soln. cooled to -30°C for several d; mixt. of initial and resiltant Zr complexes obtained;
DOI:10.1021/om300415q
