trans-potassium diaquobis(benzylmalonato)chromate(III)

Base Information

• Chemical Name: trans-potassium diaquobis(benzylmalonato)chromate(III)
• CAS No.: 79826-07-6
• Molecular Formula: C₂₀H₂₀CrO₁₀*K
• Molecular Weight: 511.467

Synonyms:

Chemical Property of trans-potassium diaquobis(benzylmalonato)chromate(III)

Chemical Property:

Purity/Quality:

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Technology Process of trans-potassium diaquobis(benzylmalonato)chromate(III)

There total 1 articles about trans-potassium diaquobis(benzylmalonato)chromate(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chromium(III) hydroxide + 2,2-dimethylmalonic acid (595-46-0) → trans-potassium diaquobis(benzylmalonato)chromate(III) (79826-07-6,82166-35-6) + trans-potassium diaquobis(dimethylmalonato)chromate(III)

Guidance literature:

With KOH; In water; treated of freshly prepd. Cr(OH)3 with twice equiv. of dimethylmalonic acid, and an equiv. of aq. KOH, mixt. was maintained at 40-50°C with vigorous stirring for a day or two; filtered, soln. was evapn. slowly in a desiccator, recrystd. from H2O, trans isomer was formed, elem. anal., cis isomer formed with rapid evapn. by rotary evaporator, recrystd. from water, elem. anal.;

upstream raw materials:

2,2-dimethylmalonic acid

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