[1,2]Thiaphospholo[2,3-b][1,2]thiaphosphorin, 3a,4-dihydro-2,6-bis(4-methylphenyl)-3a,4-bis(2-phenylethenyl)-, 8-sulfide

Base Information

• Chemical Name: [1,2]Thiaphospholo[2,3-b][1,2]thiaphosphorin, 3a,4-dihydro-2,6-bis(4-methylphenyl)-3a,4-bis(2-phenylethenyl)-, 8-sulfide
• CAS No.: 141368-97-0
• Molecular Formula: C₃₆H₃₁PS₃
• Molecular Weight: 590.814
• Mol file: 141368-97-0.mol

Synonyms:

Chemical Property of [1,2]Thiaphospholo[2,3-b][1,2]thiaphosphorin, 3a,4-dihydro-2,6-bis(4-methylphenyl)-3a,4-bis(2-phenylethenyl)-, 8-sulfide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [1,2]Thiaphospholo[2,3-b][1,2]thiaphosphorin, 3a,4-dihydro-2,6-bis(4-methylphenyl)-3a,4-bis(2-phenylethenyl)-, 8-sulfide

There total 1 articles about [1,2]Thiaphospholo[2,3-b][1,2]thiaphosphorin, 3a,4-dihydro-2,6-bis(4-methylphenyl)-3a,4-bis(2-phenylethenyl)-, 8-sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

(2E,4E)-5-phenyl-1-p-tolylpenta-2,4-dien-1-one (30313-22-5,127099-89-2) → 3a,4-Bis-((E)-styryl)-2,6-di-p-tolyl-3a,4-dihydro-[1,2]thiaphospholo[2,3-b][1,2]thiaphosphinine 8-sulfide (141368-97-0)

Guidance literature:

With tetraphosphorus decasulfide; triethylamine; In carbon disulfide; Heating;

DOI:10.1246/bcsj.65.923

Reference yield: 32.0%

3a,4-Bis-((E)-styryl)-2,6-di-p-tolyl-3a,4-dihydro-[1,2]thiaphospholo[2,3-b][1,2]thiaphosphinine 8-sulfide (141368-97-0) + methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) → 6-Methyl-5-phenyl-8-thioxo-2-p-tolyl-5,6,7,8-tetrahydro-8λ5-phosphinino[1,2-b][1,2]thiaphosphole-6-carboxylic acid methyl ester (141369-00-8)

Guidance literature:

In benzene; for 2.5h; Heating;

DOI:10.1246/bcsj.65.923

upstream raw materials:

(2E,4E)-5-phenyl-1-p-tolylpenta-2,4-dien-1-one

Downstream raw materials:

6-Methyl-5-phenyl-8-thioxo-2-p-tolyl-5,6,7,8-tetrahydro-8λ⁵-phosphinino[1,2-b][1,2]thiaphosphole-6-carboxylic acid methyl ester