phenylglyoxylic acid-((4aR)-(4ar,8at)-decahydro[1t]naphthyl ester)

Base Information

• Chemical Name: phenylglyoxylic acid-((4aR)-(4ar,8at)-decahydro[1t]naphthyl ester)
• CAS No.: 101787-81-9
• Molecular Formula: C₁₈H₂₂O₃
• Molecular Weight: 286.371
• Mol file: 101787-81-9.mol

Synonyms:

Chemical Property of phenylglyoxylic acid-((4aR)-(4ar,8at)-decahydro[1t]naphthyl ester)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenylglyoxylic acid-((4aR)-(4ar,8at)-decahydro[1t]naphthyl ester)

There total 3 articles about phenylglyoxylic acid-((4aR)-(4ar,8at)-decahydro[1t]naphthyl ester) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(4aS)-5c-hydroxy-(4ar,8at)-octahydro-naphthalen-1-one (170716-43-5) → phenylglyoxylic acid-((4aR)-(4ar,8at)-decahydro[1t]naphthyl ester) (101787-81-9)

Guidance literature:

Multi-step reaction with 2 steps

1: hydrazine hydrate; potassium hydroxide; diethylene glycol / 210 °C

2: pyridine

With pyridine; potassium hydroxide; hydrazine hydrate; diethylene glycol;

DOI:10.1002/hlca.19580410749

Reference yield:

(4aS)-4c-hydroxy-(4ar,8at)-octahydro-naphthalen-1-one (21766-50-7,63347-23-9,89576-16-9,89576-17-0,89576-18-1,134174-89-3,134174-90-6,33993-34-9) → phenylglyoxylic acid-((4aR)-(4ar,8at)-decahydro[1t]naphthyl ester) (101787-81-9)

Guidance literature:

Multi-step reaction with 2 steps

1: hydrazine hydrate; sodium methylate; methanol / 200 °C

2: pyridine

With pyridine; methanol; sodium methylate; hydrazine hydrate;

DOI:10.1002/hlca.19580410749

Reference yield:

phenylglyoxylyl chloride (25726-04-9) + 1c.9c.10t-α-Dekalol (52079-69-3,207127-50-2,691892-12-3) → phenylglyoxylic acid-((4aR)-(4ar,8at)-decahydro[1t]naphthyl ester) (101787-81-9)

Guidance literature:

With pyridine;

DOI:10.1002/hlca.19580410749

upstream raw materials:

phenylglyoxylyl chloride

1c.9c.10t-α-Dekalol

(4aS)-5c-hydroxy-(4ar,8at)-octahydro-naphthalen-1-one

(4aS)-4c-hydroxy-(4ar,8at)-octahydro-naphthalen-1-one