trans-[PtCl₂(NH=C(CH₂Cl)ON=C(C₅H₂₀))2]

Base Information

• Chemical Name: trans-[PtCl₂(NH=C(CH₂Cl)ON=C(C₅H₂₀))2]
• CAS No.: 917220-38-3
• Molecular Formula: C₁₆H₂₆Cl₄N₄O₂Pt
• Molecular Weight: 643.3
• Mol file: 917220-38-3.mol

Synonyms:

Chemical Property of trans-[PtCl₂(NH=C(CH₂Cl)ON=C(C₅H₂₀))2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-[PtCl₂(NH=C(CH₂Cl)ON=C(C₅H₂₀))2]

There total 2 articles about trans-[PtCl₂(NH=C(CH₂Cl)ON=C(C₅H₂₀))2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

cyclohexanone-oxime (100-64-1) + trans-[PtCl2(NCCH2Cl)2] (777062-62-1) → cis-[PtCl2(NH=C(CH2Cl)ON=C(C5H20))2] (917253-37-3,917220-38-3) + trans-[PtCl2(NH=C(CH2Cl)ON=C(C5H20))2] (917220-38-3,917253-37-3)

Guidance literature:

In dichloromethane; soln. of Pt-complex in CH2Cl2 added to ligand at room temp., heated withstirring at 55-60°C for 15 min; solvent evapd. under vac. to dryness, residue washed with Et2O, column chromy. on SiO2 with CH2Cl2, Et2O, solvent evapd. in vacuo, recrystd. from CH2Cl2-Et2O in air; elem. anal.;

DOI:10.1039/b611341a

Reference yield: 29.0%

cyclohexanone-oxime (100-64-1) + trans-[PtCl2(NCCH2Cl)2] (777062-62-1) → cis-[PtCl2(NH=C(CH2Cl)ON=C(C5H20))2] (917253-37-3,917220-38-3) + trans-[PtCl2(NH=C(CH2Cl)ON=C(C5H20))2] (917220-38-3,917253-37-3)

Guidance literature:

In dichloromethane; soln. of Pt-complex in CH2Cl2 added to ligand at room temp., heated withstirring at 55-60°C for 15 min; solvent evapd. under vac. to dryness, residue washed with Et2O, column chromy. on SiO2 with CH2Cl2, Et2O, solvent evapd. in vacuo, recrystd. from CH2Cl2-Et2O in air; elem. anal.;

DOI:10.1039/b611341a

upstream raw materials:

cyclohexanone-oxime

trans-[PtCl₂(NCCH₂Cl)₂]