Technology Process of (C10H8N2)2ClRu(C6H5)2PCH2P(C6H5)2RuCl(C10H8N2)2(2+)*2ClO4(1-)=(C10H8N2)2ClRu(C6H5)2PCH2P(C6H5)2RuCl(C10H8N2)2(ClO4)2
There total 1 articles about (C10H8N2)2ClRu(C6H5)2PCH2P(C6H5)2RuCl(C10H8N2)2(2+)*2ClO4(1-)=(C10H8N2)2ClRu(C6H5)2PCH2P(C6H5)2RuCl(C10H8N2)2(ClO4)2 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
ethanol;
addn. of Ru complex and Ph2PCH2PPh2 to abs. ethanol, mixture heated at reflux for 7 h under stirring, soln. cooled, addn. of LiClO4 in water; vol. of soln. reduced, addn. of water, red orange ppt. filtered, washedwith water and Et2O, dried in air, column (alumina) chromy. with CH3CN/C6H6, pptd. from CH3CN with Et2O, elem. anal.;
DOI:10.1021/ic50205a034